1,1'-(2-Iodo-5-methyl-1,3-phenylene)dinaphthalene | 824395-62-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,1'-(2-Iodo-5-methyl-1,3-phenylene)dinaphthalene
• 英文别名: 1-(2-iodo-5-methyl-3-naphthalen-1-ylphenyl)naphthalene
• CAS: 824395-62-2
• 化学式: C₂₇H₁₉I
• 分子量: 470.352
• InChiKey: AGWAKPIENQYUEY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  chlorobis(2,4,6-triisopropylphenyl)phosphine 、 1,1'-(2-Iodo-5-methyl-1,3-phenylene)dinaphthalene 在 正丁基锂 、 copper(l) chloride 作用下， 以 四氢呋喃 为溶剂， 以31%的产率得到bis(2,4,6-triisopropylphenyl)[4-methyl-2,6-di(1-naphthyl)phenyl]phosphine
  参考文献：
  名称：

  Synthesis, structure, and redox properties of crowded triarylphosphines carrying 2,6-diarylphenyl substituents

  摘要：

  Crowded triarylphosphines carrying 2,6-diarylphenyl and 2,4,6-trialkylphenyl groups were synthesized by the reaction of arylcopper(I) reagent with the chlorophosphines. The triarylphosphines had large bond angles and lengths around the phosphorus and were reversibly oxidized at significantly low potentials. X-ray crystallography of bis(2,4,6-triisopropylphenyl)[4-methyl-2,6-di(1-naphthyl)phenyl]phosphine revealed that two 1-naphthyl groups took anti conformation in the crystal. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.10.084

文献信息

• Synthesis, structure, and redox properties of crowded triarylphosphines carrying 2,6-diarylphenyl substituents
  作者：Shigeru Sasaki、Rainy Chowdhury、Masaaki Yoshifuji

  DOI：10.1016/j.tetlet.2004.10.084

  日期：2004.12

  Crowded triarylphosphines carrying 2,6-diarylphenyl and 2,4,6-trialkylphenyl groups were synthesized by the reaction of arylcopper(I) reagent with the chlorophosphines. The triarylphosphines had large bond angles and lengths around the phosphorus and were reversibly oxidized at significantly low potentials. X-ray crystallography of bis(2,4,6-triisopropylphenyl)[4-methyl-2,6-di(1-naphthyl)phenyl]phosphine revealed that two 1-naphthyl groups took anti conformation in the crystal. (C) 2004 Elsevier Ltd. All rights reserved.