10-Undecenoyl isocyanate | 404823-23-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 10-Undecenoyl isocyanate
• 英文别名: undec-10-enoyl isocyanate
• CAS: 404823-23-0
• 化学式: C₁₂H₁₉NO₂
• 分子量: 209.28
• InChiKey: KUPPNQGGRCEELW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  46.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  叠氮化钠 、 10-十一碳烯基氯酸 、 丙酮 在 甲苯 作用下， 以 水 为溶剂， 反应 4.0h， 以73.2 g of 10-undecenoyl isocyanate was obtained by distillation under reduced pressure的产率得到10-Undecenoyl isocyanate
  参考文献：
  名称：

  Thickening Or Gelling Agent For Oily Raw Materials

  摘要：

  提供了一种优秀的油稠化剂或凝胶剂。该剂与各种油兼容，并且可以通过改变添加量自由地控制油质原料或化妆品的形态或粘度。该剂含有一种新型的共改性有机聚硅氧烷，该聚硅氧烷既含有硅氧烷树枝结构的基团，又含有亲水基团，最好的聚合度为200或更高。还提供了含有共改性有机聚硅氧烷的凝胶组合物。该凝胶组合物可用作基础，以便稳定且容易制备具有各种粘弹性和形态的化妆品。油以介于液体和固体粘弹性之间的中间范围的凝胶形式保持。还提供了含有稠化或凝胶剂的化妆品。

  公开号：

  US20120269748A1

文献信息

• Thickener Or Gellant For Oil Materials, Gel Composition Comprising Same, And Method Of Producing Cosmetic Material Or Topical Agent
  申请人：Tamura Seiki

  公开号：US20120328539A1

  公开（公告）日：2012-12-27

  This inventive thickener or gellant for oil materials is characterized by comprising (A) an high molecular weight organopolysiloxane that has a polyglycerol structure-containing hydrophilic group Q and that is represented by the following structural formula (1): R 3-q (R 11 ) q Si—O—(SiR 11 2 —O) n1 —(SiR 11 Q-O) n2 —(SiR 11 L-O) n3 —Si(R) 11 ) q R 3-q wherein R 11 is a monovalent hydrocarbyl group or a hydrogen atom; L is a chain organosiloxane group, n1, n2, and n3 are numbers in the ranges 200≦n1≦1000, 0≦n2≦20, and 0≦n3≦50; R is a group selected from L and Q; q is an integer in the range from 0 to 3; wherein when n2=0, q is an integer in the range from 1 to 3 and at least one R is Q. The thickener or gellant exhibits an excellent compatibility with a variety of oil systems.

  这种用于油料的创新增稠剂或凝胶剂的特点是包含（A）高分子量的有机聚硅氧烷，具有含有聚甘油结构的亲水基团Q，并且由以下结构式（1）表示：R3-q（R11）qSi—O—（SiR112—O）n1—（SiR11Q-O）n2—（SiR11L-O）n3—Si（R）11）qR3-q其中R11是单价的烃基团或氢原子；L是链状有机硅氧烷基团，n1、n2和n3是数字范围在200≦n1≦1000，0≦n2≦20和0≦n3≦50之间；R是从L和Q中选择的一组；q是在0到3的整数范围内；当n2=0时，q是在1到3的整数范围内，并且至少有一个R是Q。该增稠剂或凝胶剂与各种油系统具有良好的相容性。
• Thickener or gellant for oil materials, gel composition comprising same, and method of producing cosmetic material or topical agent
  申请人：Tamura Seiki

  公开号：US08597619B2

  公开（公告）日：2013-12-03

  This inventive thickener or gellant for oil materials is characterized by comprising (A) an high molecular weight organopolysiloxane that has a polyglycerol structure-containing hydrophilic group Q and that is represented by the following structural formula (1): R3-q(R11)qSi—O—(SiR112—O)n1—(SiR11Q-O)n2—(SiR11L-O)n3—Si(R)11)qR3-q wherein R11 is a monovalent hydrocarbyl group or a hydrogen atom; L is a chain organosiloxane group, n1, n2, and n3 are numbers in the ranges 200≦n1≦1000, 0≦n2≦20, and 0≦n3≦50; R is a group selected from L and Q; q is an integer in the range from 0 to 3; wherein when n2=0, q is an integer in the range from 1 to 3 and at least one R is Q. The thickener or gellant exhibits an excellent compatibility with a variety of oil systems.

  这种用于油性材料的创新增稠剂或凝胶剂的特点在于包含（A）一种高分子量有机聚硅氧烷，具有含有聚甘油结构的亲水基团Q，其化学结构式（1）如下所示：R3-q(R11)qSi—O—(SiR112—O)n1—(SiR11Q-O)n2—(SiR11L-O)n3—Si(R)11)qR3-q，其中R11是单价的烃基团或氢原子；L是链状有机硅氧烷基团，n1、n2和n3是数值范围在200≦n1≦1000、0≦n2≦20和0≦n3≦50之间的数字；R是从L和Q中选择的基团；q是0到3之间的整数；当n2=0时，q是1到3之间的整数，并且至少一个R是Q。这种增稠剂或凝胶剂与各种油系统具有良好的相容性。
• THICKENING OR GELLING AGENT FOR OILY RAW MATERIALS
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP2492333A1

  公开（公告）日：2012-08-29

  [Problem] To provide an excellent oil thickening agent or gelling agent which has excellent compatibility with a variety of oil agent systems and which can freely control the form, viscosity and the like of an oil-based raw material or cosmetic composition by adjusting the added amount of the thickening agent or gelling agent. In addition, to provide a gel composition which is a base used to stably and easily produce cosmetic compositions having a variety of viscoelasticities and forms and which maintains a variety of oil agents in a gel form having an intermediate viscoelasticity between a liquid and a solid, and a cosmetic composition and the like comprising the thickening agent or gelling agent. [Means To Resolve the Problems] A thickening agent or gelling agent for an oil-based raw material, wherein the thickening agent or gelling agent has a hydrophilic group and a group having a siloxane dendron structure and which contains a novel co-modified organopolysiloxane preferably having a degree of polymerization of not lower than 200, and a topical composition or cosmetic composition containing the thickening agent or gelling agent. Furthermore, a gel composition containing the co-modified organopolysiloxane and a method for producing a cosmetic composition and the like by using the gel composition.

  问题 提供一种优良的油增稠剂或胶凝剂，该增稠剂或胶凝剂与各种油剂体系具有优良的兼容性，并且可以通过调整增稠剂或胶凝剂的添加量来自由控制油基原料或化妆品组合物的形态、粘度等。此外，提供一种凝胶组合物，该凝胶组合物是一种用于稳定、轻松地生产具有各种粘弹性和形态的化妆品组合物的基质，可将各种油剂保持在具有介于液体和固体之间的粘弹性的凝胶形态，以及一种包含该增稠剂或胶凝剂的化妆品组合物等。 [解决问题的方法］ 一种用于油基原料的增稠剂或胶凝剂，其中增稠剂或胶凝剂具有一个亲水基团和一个具有硅氧烷树枝状结构的基团，该基团含有一种新型共改性有机聚硅氧烷，其聚合度最好不低于 200，以及一种含有该增稠剂或胶凝剂的外用组合物或化妆品组合物。此外，一种含有共改性有机聚硅氧烷的凝胶组合物，以及一种使用该凝胶组合物生产化妆品组合物等的方法。
• THICKENER OR GELLANT FOR OIL MATERIALS, GEL COMPOSITION COMPRISING SAME, AND METHOD OF PRODUCING COSMETIC MATERIAL OR TOPICAL AGENT
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP2516511B1

  公开（公告）日：2014-01-22
• US8597619B2
  申请人：——

  公开号：US8597619B2

  公开（公告）日：2013-12-03