Abstract Thin films of layered perovskite compounds (CnH2n+1NH3)2(CH3NH3)m−1PbmBr3m+1 (m=1, 2 and 3) were prepared by the spin-coating method from their DMF (N,N-dimethylformamide) solutions. The control of the inorganic layer thickness in layered perovskites can be achieved by changing the ratio of the two amines (CnH2n+1NH3/CH3NH3). The layered perovskite films showed a strong, clear exciton absorption
摘要 层状
钙钛矿化合物 (CnH2n+1NH3)2(CH3NH3)m−1PbmBr3m+1 (m=1, 2 and 3) 的薄膜由其
DMF (
N,N-二甲基甲酰胺) 溶液通过旋涂法制备。层状
钙钛矿中无机层厚度的控制可以通过改变两种胺的比例(CnH2n+1NH3/CH3NH3)来实现。由于其较大的激子结合能,层状
钙钛矿薄膜在室温下显示出强烈、清晰的激子吸收峰。随着无机层数量的增加,由于转移能的降低,观察到激子吸收的红移。X 射线衍射图清楚地表明,旋涂膜垂直于表面高度取向,这分别与“单”、“双”和“三”层结构一致。