3-氯环辛烯 | 24618-80-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 3-氯环辛烯
• 英文名称: 1-chloro-2-cyclooctene
• 英文别名: 3-chlorocyclooctene；Cyclooctene, 3-chloro-
• CAS: 24618-80-2
• 化学式: C₈H₁₃Cl
• 分子量: 144.644
• InChiKey: YOFOIVOBZGXZMQ-UHFFFAOYSA-N

物化性质

• 沸点：
  196.6±19.0 °C(Predicted)
• 密度：
  0.97±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 3-氯环辛烯 以 乙醚 为溶剂， 以81%的产率得到(π-C8H13NiCl)2
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: Org.Verb.2, 2.3.2, page 318 - 321

  摘要：

  DOI：
• 作为产物：
  描述：

  cyclooctene 在 盐酸 、 双氧水 作用下， 以 水 为溶剂， 反应 2.0h， 生成 氧化环辛烯 、 3-氯环辛烯 、 1,2-二氯环辛烷
  参考文献：
  名称：

  Chlorohydrination of allyl chloride with HCl and H₂O₂ catalyzed by hollow titanium silicate zeolite to produce dichloropropanol

  摘要：

  一种新型的氯水化反应过程已经被开发，该过程使用氢氯酸和过氧化氢对丙烯氯进行催化，催化剂为空心钛硅沸石，克服了传统以氯气为基础的路线的重大缺点。

  DOI：

  10.1039/c6gc03005j

文献信息

• Heterogeneous H₂O₂-based selective oxidations over zirconium tungstate α-ZrW₂O₈
  作者：Vasilii Yu. Evtushok、Irina D. Ivanchikova、Olga V. Zalomaeva、Alexander I. Gubanov、Boris A. Kolesov、Tatiana S. Glazneva、Oxana A. Kholdeeva

  DOI：10.1039/d3dt03495j

  日期：——

  the liquid-phase selective oxidation of a range of organic substrates comprising CC, OH, S and other functional groups using aqueous hydrogen peroxide as the green oxidant. Samples of ZrW2O8 were prepared by hydrothermal synthesis and characterised by N2 adsorption, PXRD, SEM, EDX, FTIR and Raman spectroscopic techniques. Studies by IR spectroscopy of adsorbed probe molecules (CO and CDCl3) revealed

  结晶钨酸锆 ZrW 2 O 8 （这种材料主要以其各向同性负热膨胀系数而闻名）的催化性能已针对一系列包含 C 的有机底物的液相选择性氧化进行了评估 C、OH、S等官能团采用双氧水作为绿色氧化剂。采用水热合成法制备了ZrW 2 O 8样品，并通过N 2吸附、PXRD、SEM、EDX、FTIR和拉曼光谱技术对其进行了表征。对吸附探针分子（CO 和CDCl 3 ）的红外光谱研究揭示了ZrW 2 O 8表面上存在布朗斯台德酸性和碱性位点。结果表明，ZrW 2 O 8能够在温和条件下活化H 2 O 2 ，​​完成C的环氧化反应。 烯烃和不饱和酮中的C键，硫醚氧化成亚砜和砜，以及醇官能团的氧化产生酮和醛。四甲基乙烯和α-萜品烯在ZrW 2 O 8上的氧化表明分别形成了过氧化产物2,3-二甲基-3-丁烯-2-氢过氧化物和内过氧化物蛔苷，表明单线态氧参与了氧化过程。 ZrW 2 O 8催化剂在周转条件下保
• NL6409180
  申请人：——

  公开号：——

  公开（公告）日：——
• Keim, W., Diss. Aachen T. H. 1963
  作者：Keim, W.

  DOI：——

  日期：——
• Characterization of (Z)-cyclooct-2-enylstannanes
  作者：Kerry G. Penman、William Kitching、Giuseppe Tagliavini

  DOI：10.1021/om00051a022

  日期：1991.5

  (Z)-Cyclooct-2-enyltrimethylstannanes and -triphenylstannanes have been synthesized and characterized by H-1 and C-13 NMR spectra, which indicate a predominating unsymmetrical chair-boat arrangement. A mixture of the cis and trans isomers of both the (4-methylcyclooct-2-enyl)- and (8-methylcyclooct-2-enyl)trimethylstannanes (allylic stannanes) results from a sequence commencing with methylcyanocuprate opening of the monoepoxide of 1,3-cyclooctadiene, which is considered to afford regio- and stereoselectively trans-4-methylcyclooct-2-enol. Chlorination of this alcohol with both thionyl chloride and N-chlorosuccinimide/dimethyl sulfide has been conducted and the structures of the chlorides established by NMR methods and use of [1-H-2(1)]-4-methylcyclooct-2-enol. Trimethylstannylation of the chloride mixtures provides the four possible allylic stannanes, with one of the rearranged 8-methyl isomers slightly predominating. NMR spectra of various fractions from preparative gas chromatography have been obtained, and full assignment of the C-13 NMR spectra of the isomers is reported. Acidolysis of these fractions (with CF3COOD) proceeds rapidly to yield mixtures of H-2-substituted 3- and 4-methylcyclooctenes, but only one diastereomer of each system appears to be formed, on the basis of the C-13 NMR spectra. This implies that electrophile approach to the pi-face at the gamma-carbon is not influenced by the orientation of the C-Sn bond but is probably dictated by the predominant molecular conformation.
• η³-Allylpalladium Complexes from Medium-Ring Cycloalkenes
  作者：Jean-Marie Rosset、Matthew P. Glenn、John D. Cotton、Anthony C. Willis、Colin H. L. Kennard、Karl A. Byriel、Bruce H. Riches、William Kitching

  DOI：10.1021/om971132c

  日期：1998.5.1

  The dimeric eta(3)-allylpalladium chloride complexes formed from various cycloalkenes (C-7-C-13) and some methyl-and tert-butyl-substituted cycle alkenes have be en characterized by H-1 and C-13 NMR spectroscopy and in selected cases by X-ray crystallography. The formation of syn and anti isomers in the larger ring systems is demonstrated, and complexes with a rearranged ring system are formed from tert-butylcyclodecene and tert-butylcyclododecene. The sesquiterpene, carophyllene, is shown to form an eta(3)-allyl exocyclic complex, exclusively from the (E)-double bond. Cis and trans isomers, with respect to allyl group orientation in these halo-bridged dimers, have been identified by low-temperature (190K) NMR spectroscopy, and their interconversion (Delta G(double dagger) approximate to 11 kcal/mol) is considered to involve a "cubic" eta(3)-allylpalladium chloride tetramer.