| 1065654-85-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1065654-85-4
• 化学式: C₇₆H₆₈O₄Si
• 分子量: 1073.46
• InChiKey: WPQRMHXFLCRVCN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.35
• 重原子数：
  81.0
• 可旋转键数：
  11.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  52.6
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Formation of double helix self-assembled monolayers of ethynylhelicene oligomer disulfides on gold surfaces

  摘要：

  Optically active ethynylhelicene pentamers and hexamers linked by disulfide bonds were synthesized. They formed self-assembled monolayers (SAMs) with double helix structure on gold surfaces, which were analyzed by infrared reflection-absorption spectroscopy (IR-RAS), quartz crystal microbalance (QCM), surface plasmon resonance (SPR), and circular dichroism (CD). Double helix SAMs could be formed on gold surfaces either from double helices or random coils in solution. The double helices on the surface were more stable than in solution. This result suggested the presence of strong intercomplex interactions between double helix complexes on the surface. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.06.024
• 作为产物：
  描述：

  decyl (M)-3-[1',12'-dimethyl-8'-(trimethylsilylethynyl)benzo[c]phenanthryl-5'-ethynyl]-5-trifluoromethanesulfoxybenzoate 、 在 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 copper(l) iodide 、 三异丙叉丙酮基膦 、 四丁基碘化铵 、 三乙胺 、 三苯基膦 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Formation of double helix self-assembled monolayers of ethynylhelicene oligomer disulfides on gold surfaces

  摘要：

  Optically active ethynylhelicene pentamers and hexamers linked by disulfide bonds were synthesized. They formed self-assembled monolayers (SAMs) with double helix structure on gold surfaces, which were analyzed by infrared reflection-absorption spectroscopy (IR-RAS), quartz crystal microbalance (QCM), surface plasmon resonance (SPR), and circular dichroism (CD). Double helix SAMs could be formed on gold surfaces either from double helices or random coils in solution. The double helices on the surface were more stable than in solution. This result suggested the presence of strong intercomplex interactions between double helix complexes on the surface. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.06.024