[Ti(η5-C5H4Li)(η8-C8H7Li)]*(N,N,N',N'',N''-pentamethyldiethylenetriamine) | 1288985-56-7

• 英文名称: [Ti(η5-C5H4Li)(η8-C8H7Li)]*(N,N,N',N'',N''-pentamethyldiethylenetriamine)
• 英文别名: [Ti(η5-C5H4Li)(η8-C8H7Li)]*pmdta
• CAS: 1288985-56-7
• 化学式: C₄₄H₆₈Li₄N₆Ti₂
• 分子量: 804.588
• InChiKey: ZKDMJIXYQAQZTB-BSRPRXGZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ti(η5-C5H4Li)(η8-C8H7Li)]*(N,N,N',N'',N''-pentamethyldiethylenetriamine) 、 1,2-dichlorotetra-tert-butyldistannane 以 正己烷 为溶剂， 生成 [Ti(η5-C5H4)(η8-C8H7)Sn2tBu4]
  参考文献：
  名称：

  Selective Dilithiation of [Ti(η⁵-C₅H₅)(η⁸-C₈H₈)] and Subsequent Conversion into Neutral and Cationicansa-Complexes

  摘要：

  Selective dimetalation of a sandwich complex featuring the cyclooctatetraene ligand has been accomplished for the first time. The isolation of the dilithiated species 1 subsequently enabled the isolation of a paramagnetic [2] stannatitanoarenophane (2) via salt elimination reaction. Chemical oxidation resulted in the formation of a rare example of a cationic ansa-complex (3).

  DOI：

  10.1021/ja2014218
• 作为产物：
  描述：

  正丁基锂 、 (η⁸-cyclooctatetraene)(η⁵-cyclopentadyenyl)titanium 、 五甲基二乙烯三胺 以 正己烷 为溶剂， 以98%的产率得到[Ti(η5-C5H4Li)(η8-C8H7Li)]*(N,N,N',N'',N''-pentamethyldiethylenetriamine)
  参考文献：
  名称：

  Selective Dilithiation of [Ti(η⁵-C₅H₅)(η⁸-C₈H₈)] and Subsequent Conversion into Neutral and Cationicansa-Complexes

  摘要：

  Selective dimetalation of a sandwich complex featuring the cyclooctatetraene ligand has been accomplished for the first time. The isolation of the dilithiated species 1 subsequently enabled the isolation of a paramagnetic [2] stannatitanoarenophane (2) via salt elimination reaction. Chemical oxidation resulted in the formation of a rare example of a cationic ansa-complex (3).

  DOI：

  10.1021/ja2014218