| 141520-97-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• CAS: 141520-97-0
• 化学式: C₃F₉N₂O
• 分子量: 251.031
• InChiKey: DJJYPWDBNRPVPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.41
• 重原子数：
  15.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26.38
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  三氟亚硝基甲烷 、 perfluoro-(2,4,4,7,7,9-hexamethyl-3,8-dioxa-2,5,6,9-tetra-azadec-5-ene) 以 四氯化碳 为溶剂， 生成
  参考文献：
  名称：

  Decomposition of perfluoro- (2,4,4,7,7,9 -hexamethyl- 3,8-dioxa-2,5,6,9-tetra-azadec-5-ene) in the presence of fluoroalkenes, ethyne, benzene and nitroso compounds

  摘要：

  Thermolysis of the azo compound (CF3)2NOC(CF3)2N = NC(CF3)2ON(CF3)2 (1) alone at 140-degrees-C gives nitrogen, hexafluoroacetone and the hydrazine (CF3)2NN(CF3)2 via (CF3)2N. radical coupling in quantitative yield, while from decomposition in the presence of the alkenes CF2 = CCl2, CF2 = CFCl and CF2 = CHF (ca. 1:1 molar ratio) the major products are the dimer [(CF3)2NCF2CCl2]2, trimer (CF2)2N(CF2CFCl)2CFClCF2N)CF3)2 and a mixture of tetramers (CF3)2N(C2HF3)4N(CF3)2, respectively. The (CF3)2N. radicals generated from 1 can also be trapped with bromine [ --> (CF3)2NBr] and nitroso compounds [ --> (CF3)2NNRO.(R = CF3 and Ph)], but with ethyne or benzene near-quantitative yields of the amine (CF3)2NH are obtained.

  DOI：

  10.1016/s0022-1139(00)80120-7