3,3'-(((2-hydroxy-5-methyl-1,3-phenylene)bis(methaneylylidene))bis(hydrazin-1-yl-2-ylidene))bis(quinoxaline-2(1H)-thione) | 1252675-38-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 3,3'-(((2-hydroxy-5-methyl-1,3-phenylene)bis(methaneylylidene))bis(hydrazin-1-yl-2-ylidene))bis(quinoxaline-2(1H)-thione)
• CAS: 1252675-38-9
• 化学式: C₂₅H₂₀N₈OS₂
• 分子量: 512.619
• InChiKey: UXZWWQYIUWBIIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  36.0
• 可旋转键数：
  6.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  126.37
• 氢给体数：
  5.0
• 氢受体数：
  9.0

反应信息

• 作为产物：
  描述：

  3-肼基-2(1H)-喹喔啉硫酮 、 2,6-二甲酰-4-甲基苯酚 以 甲醇 为溶剂， 反应 2.0h， 以79%的产率得到3,3'-(((2-hydroxy-5-methyl-1,3-phenylene)bis(methaneylylidene))bis(hydrazin-1-yl-2-ylidene))bis(quinoxaline-2(1H)-thione)
  参考文献：
  名称：

  Spectroscopy, structure, and electrochemistry of transition metal complexes having [M₂N₂OS₂] coordination sphere

  摘要：

  Binuclear transition metal complexes of bicompartmental SNONS donors were synthesized and characterized by various physico-chemical techniques. Two different precursors with chloromethyl/formyl functionality at the 2 and 6 positions of phenolate ring are used to construct the ligands. The quinoxaline scaffolds provide SN donors incorporated at the 2 and 6 positions. Copper and zinc complexes are square pyramidal, whereas nickel and cobalt complexes are octahedral. The influence of two metal centers in terms of cooperative effect on the electronic, magnetic, electrochemical, and structural properties was investigated.

  DOI：

  10.1080/00958972.2010.511201