diammine(pyrazine-2,3-dicarboxylato-N,O)palladium(II) | 190589-54-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: diammine(pyrazine-2,3-dicarboxylato-N,O)palladium(II)
• CAS: 190589-54-9
• 化学式: C₆H₈N₄O₄Pd
• 分子量: 306.574
• InChiKey: AFBKDOVOSAMVLL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,3-吡嗪二羧酸 、 氨 、 palladium dichloride 以 not given 为溶剂， 以55%的产率得到diammine(pyrazine-2,3-dicarboxylato-N,O)palladium(II)
  参考文献：
  名称：

  Diammine (pyrazine-2,3-dicarboxylato-N,O) palladium(II): synthesis, crystal structure, spectroscopic and thermal properties

  摘要：

  The synthesis, crystal structure and spectroscopic (IR, XPS) characterization of a new Pd complex with 2,3-pyrazinedicarboxylic acid (2,3-H(2)pzdc), Pd(2,3-pzdc)(NH3)(2) (1), are reported. This compound crystallizes in the monoclinic space group P2(1)/c with four molecules in the unit cell. Using 2697 independent reflections up to 2 theta=60 degrees, the structure was refined to R = 0.044. The lattice is formed of isolated zwitterionic moieties in which the square-planar coordination of palladium is ensured by three nitrogen atoms and one oxygen from a carboxylate group attached to the pyrazine ring. Both the structural and the infrared data confirm the absence of a polymeric network. Thermal degradation under nitrogen produces a mixture of palladium metal and PdO at 773 K. The XPS data of 1 are discussed together with those of a related compound with 3,5-pyrazoledicarboxylic acid (H(3)Dcp), (NBu4)(2)[Pd-2(Dcp)(2)] (2) and suggest the presence of a delocalized positive charge in the pyrazine ring.

  DOI：

  10.1016/s0020-1693(96)05533-8