2-溴-5H-苯并呋喃[3,2-C]咔唑 | 1377576-72-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 中文名称: 2-溴-5H-苯并呋喃[3,2-C]咔唑
• 英文名称: 2-bromo-5H-benzofuro[3,2-c]carbazole
• 英文别名: 2-bromo-5H-[1]benzofuro[3,2-c]carbazole
• CAS: 1377576-72-1
• 化学式: C₁₈H₁₀BrNO
• 分子量: 336.187
• InChiKey: PNCRMWDBWKXNCY-UHFFFAOYSA-N

物化性质

• 沸点：
  550.8±30.0 °C(Predicted)
• 密度：
  1.654±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.9
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-溴-5H-苯并呋喃[3,2-C]咔唑 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 Pd(pph3)Cl₄ 、 potassium carbonate 、 sodium t-butanolate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 60.0h， 生成 2-(9-Phenylcarbazol-3-yl)-5-(9,9'-spirobi[fluorene]-4-yl)-[1]benzofuro[3,2-c]carbazole
  参考文献：
  名称：

  ORGANIC COMPOUND, AND ORGANIC LIGHT EMITTING DIODE AND ORGANIC LIGHT EMITTING DISPLAY DEVICE INCLUDING THE SAME

  摘要：

  本发明提供了一种用于有机发光二极管的有机化合物。该有机化合物的一个示例如下：

  公开号：

  US20180130953A1
• 作为产物：
  描述：

  1,3-二溴苯 在 四(三苯基膦)钯 、 硫酸 、 硝酸 、 potassium carbonate 、 三苯基膦 作用下， 以 乙醇 、 水 、 邻二氯苯 、 甲苯 为溶剂， 反应 14.5h， 生成 2-溴-5H-苯并呋喃[3,2-C]咔唑
  参考文献：
  名称：

  ORGANIC COMPOUND, AND ORGANIC LIGHT EMITTING DIODE AND ORGANIC LIGHT EMITTING DISPLAY DEVICE INCLUDING THE SAME

  摘要：

  本发明提供了一种用于有机发光二极管的有机化合物。该有机化合物的一个示例如下：

  公开号：

  US20180130953A1

文献信息

• [EN] NOVEL COMPOUND FOR ORGANIC ELECTRONIC MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] COMPOSÉ INÉDIT POUR MATÉRIAU ÉLECTRONIQUE ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE L'UTILISANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2012067425A1

  公开（公告）日：2012-05-24

  Provided are a novel compound for an organic electronic material and an organic electroluminescent device using the same. The compound for an organic electronic material according to the present invention has high electron transport efficiency, thereby preventing crystallization at the time manufacturing of a device, and allows a layer to be easily formed, thereby improving current characteristics of the device, and thus an OLED device having a lowered driving voltage and improved power efficiency as well as superior luminous efficiency and lifespan characteristics as compared with the existing material can be manufactured.

  提供了一种用于有机电子材料的新型化合物，以及使用该化合物的有机电致发光器件。根据本发明的有机电子材料化合物具有高电子传输效率，从而在制造器件时防止结晶，并且允许层易于形成，从而提高器件的电流特性，因此，与现有材料相比，可以制造出具有降低驱动电压和改善功率效率以及优越的发光效率和寿命特性的OLED器件。
• COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT MATERIAL, ORGANIC ELECTROLUMINESCENT ELEMENT, AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20180029983A1

  公开（公告）日：2018-02-01

  Disclosed herein is a compound represented by formula (1): A-L-B, wherein: A is a group represented by formula (1-A); B is a group represented by formula (1-B); L is a single bond, a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heteroarylene group having 5 to 50 ring atoms; and L is bonded to one of R 1 to R 4 of formula (1-A) and R 11 to R 14 of formula (1-B); in which the groups Q 1 , Q 2 , L 1 , L 2 , R 1 -R 4 , R 11 -R 14 , R a -R d and R e -R h defined herein. Also disclosed herein are materials and devices containing the compound represented by formula (1).

  本文披露了一种由化学式（1）表示的化合物：A-L-B，其中：A是由化学式（1-A）表示的基团；B是由化学式（1-B）表示的基团；L是单键，具有6到50个环碳原子的取代或未取代芳基基团，或具有5到50个环原子的取代或未取代杂芳基基团；并且L与化学式（1-A）的R1至R4中的一个和化学式（1-B）的R11至R14中的一个键合；其中本文定义了基团Q1、Q2、L1、L2、R1-R4、R11-R14、Ra-Rd和Re-Rh。本文还披露了含有由化学式（1）表示的化合物的材料和器件。
• Organic light emitting compounds and organic light emitting devices including the same
  申请人：SFC CO., LTD.

  公开号：US11075343B2

  公开（公告）日：2021-07-27

  Disclosed is an organic light emitting compound represented by Formula 1: HAr1—(L)n—HAr2  (1); an organic light emitting device including the organic light emitting compound of Formula 1: and an organic light emitting device including the organic light emitting compound of Formula 1 as a first compound and a second compound represented by Formula 2: HAr3—(L)n—HAr4  (2) .

  本发明公开了一种由式 1 表示的有机发光化合物： HAr1-(L)n-HAr2 (1)； 包括式 1 有机发光化合物的有机发光器件：以及 一种有机发光器件，包括作为第一化合物的式 1 有机发光化合物和由式 2 代表的第二化合物： HAr3-(L)n-HAr4 (2) .
• NOVEL COMPOUND FOR ORGANIC ELECTRONIC MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：Shin Hyo Nim

  公开号：US20140077179A1

  公开（公告）日：2014-03-20

  Provided are a novel compound for an organic electronic material and an organic electroluminescent device using the same. The compound for an organic electronic material according to the present invention has high electron transport efficiency, thereby preventing crystallization at the time manufacturing of a device, and allows a layer to be easily formed, thereby improving current characteristics of the device, and thus an OLED device having a lowered driving voltage and improved power efficiency as well as superior luminous efficiency and lifespan characteristics as compared with the existing material can be manufactured.
• ORGANIC LIGHT EMITTING COMPOUNDS AND ORGANIC LIGHT EMITTING DEVICES INCLUDING THE SAME
  申请人：SFC CO., LTD.

  公开号：US20170207397A1

  公开（公告）日：2017-07-20

  Disclosed is an organic light emitting compound represented by Formula 1: HAr 1 -(L) n -HAr 2 (1) Also disclosed is an organic light emitting device including the organic light emitting compound of Formula 1. Also disclosed is an organic light emitting device including the organic light emitting compound of Formula 1 as a first compound and a second compound represented by Formula 2: HAr 3 -(L) n -HAr 4 (2) The organic light emitting devices exhibit low driving voltage, high efficiency, and long life. Due to these advantages, the organic light emitting devices are useful in a variety of industrial applications, including displays and lighting systems.