iodo(phthalocyaninato)vanadium(III) | 219691-25-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: iodo(phthalocyaninato)vanadium(III)
• CAS: 219691-25-5
• 化学式: C₃₂H₁₆IN₈V
• 分子量: 690.379
• InChiKey: NWTHPEMZZKOQHR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  钒 、 碘 、 1,2-二氰基苯 以 neat (no solvent) 为溶剂， 生成 iodo(phthalocyaninato)vanadium(III)
  参考文献：
  名称：

  Iodo(phthalocyaninato)vanadium(III)

  摘要：

  A new vanadium phthalocyanine complex with the formula [VI(C32H16N8)], or PcVI (Pc = C32H16N8), has been obtained by the reaction of pure V powder with 1,2-dicyanobenzene under iodine vapour. The V atom is bonded to one apical iodide ligand and four N-isoindole atoms, and has square-pyramidal coordination geometry. The mean V-N-isoindole distance is 1.952 (3) Angstrom. The VI bond has a length of 2.6279 (8) Angstrom and is tilted 1.7 (1)degrees to the normal of the plane formed by the four N-isoindole atoms. The phthalocyaninato ligand is saucer-shaped.

  DOI：

  10.1107/s0108270198008105