9-(9H-carbazol-3-yl)-N,N-diphenylcarbazol-3-amine | 883224-27-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 9-(9H-carbazol-3-yl)-N,N-diphenylcarbazol-3-amine
• CAS: 883224-27-9
• 化学式: C₃₆H₂₅N₃
• 分子量: 499.615
• InChiKey: GTXUOBPKEOMLQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  39
• 可旋转键数：
  4
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-(9H-carbazol-3-yl)-N,N-diphenylcarbazol-3-amine 、 4-碘苯甲醚 在 18-冠醚-6 、 铜 、 potassium carbonate 作用下， 以 邻二氯苯 为溶剂， 反应 24.0h， 以34%的产率得到C₄₃H₃₁N₃O
  参考文献：
  名称：

  Well Defined Carbazol-3,9-Diyl Based Oligomers as Host Materials for Organic Electro-Phosphorescent Devices

  摘要：

  Well defined carbazol-3,9-diyl-based derivatives as host materials for electrophosphorescent devices have been synthesized by the modified Ullmann reaction as a key step. The full characterization. of their structure by mass spectrometry, infrared absorption and proton magnetic resonance spectroscopy is presented. The amorphous compounds with glass transition temperatures of 103-154 degrees C possess high thermal stability with onset decomposition temperatures exceeding 360 degrees C. Conjugation of the 3,9-linked systems is rather confined within one carbazole unit, retaining large triplet energies suitable for green. and red electro-phosphorescence. Using the new host material, efficient green phosphorescent organic light emitting diodes was demonstrated.

  DOI：

  10.1080/15421400701229495
• 作为产物：
  描述：

  3-碘咔唑 、 二苯胺 在 18-冠醚-6 、 铜 、 potassium carbonate 作用下， 生成 9-(9H-carbazol-3-yl)-N,N-diphenylcarbazol-3-amine
  参考文献：
  名称：

  Well Defined Carbazol-3,9-Diyl Based Oligomers as Host Materials for Organic Electro-Phosphorescent Devices

  摘要：

  Well defined carbazol-3,9-diyl-based derivatives as host materials for electrophosphorescent devices have been synthesized by the modified Ullmann reaction as a key step. The full characterization. of their structure by mass spectrometry, infrared absorption and proton magnetic resonance spectroscopy is presented. The amorphous compounds with glass transition temperatures of 103-154 degrees C possess high thermal stability with onset decomposition temperatures exceeding 360 degrees C. Conjugation of the 3,9-linked systems is rather confined within one carbazole unit, retaining large triplet energies suitable for green. and red electro-phosphorescence. Using the new host material, efficient green phosphorescent organic light emitting diodes was demonstrated.

  DOI：

  10.1080/15421400701229495