Cp2Zr(P(H)B(NiPr2)[N(SiMe3)2])2 | 327174-80-1

• 英文名称: Cp2Zr(P(H)B(NiPr2)[N(SiMe3)2])2
• CAS: 327174-80-1
• 化学式: C₃₄H₇₆B₂N₄P₂Si₄Zr
• 分子量: 828.14
• InChiKey: LUMTWFCBNFVMKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) 、 Cp2Zr(P(H)B(NiPr2)[N(SiMe3)2])2 以 正己烷 为溶剂， 以45%的产率得到Cp2Zr(P(H)B(NiPr2)[N(SiMe3)2])2Mo(CO)4
  参考文献：
  名称：

  Synthesis and coordination behavior of a zirconocene bis(borylphosphane)

  摘要：

  The reaction of LiP(H)B((NPr2)-Pr-i)[N(SiMe3)(2)]. DME with Cp2ZrCl2, in a 2:1 ratio yields the metallodiphosphane Cp2Zr{P(H)B-(NiPr2)[N(SiMe3)(2)]}(2) (3a). Combination of 3a with Mo(CO)(4) (norbornadiene) provides the adduct Cp2Zr{P(H)B((NPr2)-Pr-i)-[N(SiMe3)(2)]}(2). Mo(CO)(4) (4a) in which the metallo-diphosphane 3a acts as a chelating ligand. The compounds have been characterized by spectroscopic methods and the molecular structures of 3a and 4a have been determined by single-crystal X-ray diffraction methods. The chemical and structural features are compared and contrasted with related metallo-diphosphanes that contain organic substituents on the diphosphane P atoms. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00561-1
• 作为产物：
  描述：

  二氯二茂锆 、 LiP(H)B(NiPr2)[N(SiMe3)2]*DME 以 正己烷 为溶剂， 以66%的产率得到Cp2Zr(P(H)B(NiPr2)[N(SiMe3)2])2
  参考文献：
  名称：

  Synthesis and coordination behavior of a zirconocene bis(borylphosphane)

  摘要：

  The reaction of LiP(H)B((NPr2)-Pr-i)[N(SiMe3)(2)]. DME with Cp2ZrCl2, in a 2:1 ratio yields the metallodiphosphane Cp2Zr{P(H)B-(NiPr2)[N(SiMe3)(2)]}(2) (3a). Combination of 3a with Mo(CO)(4) (norbornadiene) provides the adduct Cp2Zr{P(H)B((NPr2)-Pr-i)-[N(SiMe3)(2)]}(2). Mo(CO)(4) (4a) in which the metallo-diphosphane 3a acts as a chelating ligand. The compounds have been characterized by spectroscopic methods and the molecular structures of 3a and 4a have been determined by single-crystal X-ray diffraction methods. The chemical and structural features are compared and contrasted with related metallo-diphosphanes that contain organic substituents on the diphosphane P atoms. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00561-1