CuCl*AA | 190724-29-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: CuCl*AA
• CAS: 190724-29-9
• 化学式: C₃H₇N*Cl*Cu
• 分子量: 156.094
• InChiKey: HGBFMYYILJMDFB-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  丙烯胺 、 copper dichloride 以 乙醇 为溶剂， 生成 CuCl*AA
  参考文献：
  名称：

  Heterophase Reactions of Hydrazine Vapor with Copper(I) π-Complexes at the Surface of a Piezoelectric Quartz Crystal

  摘要：

  Quartz Crystal Microbalance (QCM) was used to study heterophase reactions of hydrazine vapor with solid copper(I) pi-complexes Cu2Cl2 (.) DVB, CuCl (.) AA, (HDAA)CuCl2, and Cu(HMA) (.) H2O (where DVB is CH2=CH-C6H4-CH=CH2, AA is CH2=CH-CH2-NH2, HDAA is (CH2=CH-CH2)(2)NH2+, and HMA is the HOOC-CH=CH-COO-. It was found that all the complexes can add hydrazine reversibly. However, in contrast to ionic complexes, molecular complexes gradually decomposed while reacting with the vapor of N2H4. The kinetic parameters such as the rate constants of forward and reverse heterophase reactions were determined. Complex Cu(HMA) (.) H2O was found to be most sensitive to the vapor of N2H4.

  DOI：

  10.1023/b:ruco.0000026000.29539.7a