bis[O-methylchloroaluminum-1-phenyl-2-(1,3,5-dithiazinan-5-yl)ethanolate] | 633336-06-8

• 英文名称: bis[O-methylchloroaluminum-1-phenyl-2-(1,3,5-dithiazinan-5-yl)ethanolate]
• CAS: 633336-06-8
• 化学式: C₂₄H₃₄Al₂Cl₂N₂O₂S₄
• 分子量: 635.679
• InChiKey: DKMZPYQQIOHEMG-KPCUFKOXSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二甲基氯化铝 、 (+/-)-2-(1,3,5-dithiazinan-5-yl)-1-phenylethanol 以 正己烷 、 甲苯 为溶剂， 以95%的产率得到bis[O-methylchloroaluminum-1-phenyl-2-(1,3,5-dithiazinan-5-yl)ethanolate]
  参考文献：
  名称：

  Organometallic Aluminum Compounds Derived from 2-(1,3,5-Dithiazinan-5-yl)ethanol Ligands¹

  摘要：

  The reactions of AIMe(2)Y (Y = Me or Cl) with new ligands 2-(1,3,5-dithiazinan-5-yl)ethanol (1), 2-(1,3,5-dithiazinan-5-yl)-1 -methylethanol (2), and 2-(1,3,5-dithiazinan-5-yl)-1 -phenylethanol (3) are described. The ligands are coordinated to aluminum atoms by nitrogen and oxygen atoms, with a nitrogen based spiranic structure. Equimolar reactions gave dimeric structures bearing pentacoordinated aluminum atoms a(AIMeY)-2-(1,3,5-dithiazinan-5-yl)ethanolates (4-7) as well as monometallic compounds with tetracoordinated aluminum atoms a(AIMeY)-2-(1,3,5-dithiazinan-5-yl)ethanolates (8-9). Reactions with 2 equiv of the aluminum reagents afforded tetracoordinated dialuminum complexes O-(AIMeY)-O-(AIMe(2)y)-2-(1,3,5-dithiazinan-5-yl)ethanolate (10-18). The structures of the new compounds were determined by NMR (H-1,C-13, and Al-27) and complemented by X-ray diffraction of compounds 4, 10, and 16-18. Relevant intermolecular interactions C-(HS)-S-..., C-(HCl)-Cl-..., and C-H(...)pi found in the crystalline network are reported.

  DOI：

  10.1021/ic034642+