1'-(diphenylthiophosphoryl)-1-(2,2-dibromovinyl)ferrocene | 904690-33-1

• 英文名称: 1'-(diphenylthiophosphoryl)-1-(2,2-dibromovinyl)ferrocene
• CAS: 904690-33-1
• 化学式: C₂₄H₁₉Br₂FePS
• 分子量: 586.11
• InChiKey: IOKVRWSGVWDBLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  1'-(diphenylthiophosphoryl)-1-(2,2-dibromovinyl)ferrocene 、 ammonium chloride 、 乙酸乙酯 在 BuLi 作用下， 以 四氢呋喃 为溶剂， 以82%的产率得到[1'-(diphenylthiophosphoryl)ferrocenyl]ethyne*0.33(ethyl acetate)
  参考文献：
  名称：

  Synthesis of [1′-(diphenylthiophosphoryl)ferrocenyl]ethyne and alkyne-metal complexes thereof

  摘要：

  The novel functionalized ferrocene, alkyne Ph2P(S)fcC CH (1; fc = ferrocene-1,1'-diyl) was synthesized from Ph2P(S)fcCHO (6) via the Corey-Fuchs reaction. It was further reacted with K-2[HgI4]KOH to give mercury(II) acetylide Hg{C CfcP(S)Ph-2}(2) (8), and with [Co-2(CO)(8)] to afford the trimetallic CO2Fe complex [(mu-eta(2): eta(2)-1){Co(CO)(3)}(2)](Co-Co) (9). All compounds were characterized by spectral methods (IR, NMR, and MS) and by combustion or high-resolution MS elemental analyses. In addition, the crystal structures of 1, Ph(2)PfcBr (5), 6, Ph2P(S)fcCH=CBr2 (7), and 9 were determined by single-crystal X-ray diffraction. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.02.027
• 作为产物：
  描述：

  四溴化碳 、 1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde 在 PPh₃ 、 NaHCO₃ 、 H₂O₂ 作用下， 以 二氯甲烷 为溶剂， 以83%的产率得到1'-(diphenylthiophosphoryl)-1-(2,2-dibromovinyl)ferrocene
  参考文献：
  名称：

  Synthesis of [1′-(diphenylthiophosphoryl)ferrocenyl]ethyne and alkyne-metal complexes thereof

  摘要：

  The novel functionalized ferrocene, alkyne Ph2P(S)fcC CH (1; fc = ferrocene-1,1'-diyl) was synthesized from Ph2P(S)fcCHO (6) via the Corey-Fuchs reaction. It was further reacted with K-2[HgI4]KOH to give mercury(II) acetylide Hg{C CfcP(S)Ph-2}(2) (8), and with [Co-2(CO)(8)] to afford the trimetallic CO2Fe complex [(mu-eta(2): eta(2)-1){Co(CO)(3)}(2)](Co-Co) (9). All compounds were characterized by spectral methods (IR, NMR, and MS) and by combustion or high-resolution MS elemental analyses. In addition, the crystal structures of 1, Ph(2)PfcBr (5), 6, Ph2P(S)fcCH=CBr2 (7), and 9 were determined by single-crystal X-ray diffraction. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.02.027