[(1-phenylazo-2-ethyl-sulfanyl benzene(1-)) platinum(IV) (iodide)3] | 913069-20-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [(1-phenylazo-2-ethyl-sulfanyl benzene(1-)) platinum(IV) (iodide)3]
• CAS: 913069-20-2
• 化学式: C₁₄H₁₃I₃N₂PtS
• 分子量: 817.13
• InChiKey: LEVQDUXLDIGCCV-JEEAYVPESA-K

反应信息

• 作为产物：
  描述：

  potassium tetraiodoplatinate 、 1-phenylazo-2-ethyl-sulfanyl benzene 以 甲醇 、 水 为溶剂， 以80%的产率得到[(1-phenylazo-2-ethyl-sulfanyl benzene(1-)) platinum(IV) (iodide)3]
  参考文献：
  名称：

  Synthesis and characterization of new Pt(II) and Pt(IV) orthometallated complexes incorporating 1-arylazo-2-ethyl sulfanyl benzene

  摘要：

  The new ligands 1-arylazo-2-ethyl sulfanyl benzene, LH (1) [LH is 2-(RC6H4-N=N)C6H4SEt; R =p-H (for (LH)-H-1), p-Me (for (LH)-H-2) and p-Cl (for (LH)-H-3), H of LH represents the dissociable proton upon orthometallation] and their orthoplatinated complexes of the type Pt-II(L)Cl have been synthesized by the reaction of LH with K2PtCl4 where [L](-) ligands bind the metal in a tridentate (C, N, S) fashion. On the other hand, new platinum (IV) cyclometallates, Pt-IV(L)I-3, were obtained directly on treating K2PtI4 with LH. The complexes and ligands were characterized from spectroscopic data. The X-ray structure of Pt(L)I-3 authenticated its formation. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.02.015