dichloro(2-acetyl-1,10-phenanthroline(2,6-difluoroanil))nickel(II) | 913341-33-0

• 英文名称: dichloro(2-acetyl-1,10-phenanthroline(2,6-difluoroanil))nickel(II)
• CAS: 913341-33-0
• 化学式: C₂₀H₁₃Cl₂F₂N₃Ni
• 分子量: 462.936
• InChiKey: JXZOONPFICCGLW-VFTBONLLSA-L

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 2-acetyl-1,10-phenanthroline 2,6-difluoroanil 以 乙醇 为溶剂， 以83%的产率得到dichloro(2-acetyl-1,10-phenanthroline(2,6-difluoroanil))nickel(II)
  参考文献：
  名称：

  Synthesis, characterization and ethylene oligomerization studies of nickel complexes bearing 2-imino-1,10-phenanthrolines

  摘要：

  A series of nickel (11) complexes ligated by 2-imino-1,10-phenanthrolines were synthesized and characterized by elemental and spectroscopic analysis as well as by single-crystal X-ray crystallography. X-ray crystallographic analysis reveals complexes 3, 5, 7 and 11 as the five-coordinated distorted trigonal-bipyramidal geometry. Upon activation with Et(2)AlCl, these complexes exhibited considerably high activity for ethylene oligomerization (up to 3.76 x 10(7) g mol(-1) (Ni) h(-1) for 12 with 10 equiv. of PPh(3)). The ligand environment and reaction conditions significantly affect the catalytic activity of their nickel complexes. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.06.028