| 234078-94-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 234078-94-5
• 化学式: C₄₅H₅₅O₅V
• 分子量: 726.87
• InChiKey: GWJJDVRJMUNZPR-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三乙基铝 以 toluene 为溶剂， 生成 、
  参考文献：
  名称：

  EPR Monitoring of Vanadium(IV) Species Formed upon Activation of Vanadium(V) Polyphenolate Precatalysts with AlR₂Cl and AlR₂Cl/Ethyltrichloroacetate (R = Me, Et)

  摘要：

  Reactions of the vanadyl polyphenolate complexes {VO[p-tert-butylcalix[4]arene(O)(3)(OMe)]) (1) and [VO(OArCH2Ar'CH2OAr)](2) (Ar = 4,6-tert-butylphenol; Ar' = 4-tert-butylphenol) (2) with AlR3 and AlR2Cl, in the absence and in the presence of reactivator (ethyltrichloroacetate, ETA), were monitored by EPR (R = Me, Et). It was shown, that vanadium(IV) complexes with proposed structures (LtVR)-R-IV(AlR3) and (LIVR)-R-IV(AlR2Cl) are formed upon interaction of 1 with AlR3 and AlR2Cl, respectively (20 degrees C, L-1 is the initial oxo-calix[4]arene ligand). Similarly, vanadium(IV) complexes with proposed structures (L2VR)-R-IV(AlR3) and (L2VR)-R-IV(AlR2Cl) are formed upon interaction or 2 with AlR3 and AlR2Cl (L-2 is the initial ligand of 2). The growth of the concentration of (L1VR)-R-IV(AlR2Cl) and (L2VR)-R-IV(AlR2Cl) correlates with the increase of the ethylene polymerization activity of the catalyst systems 1,2/AlR2Cl/ETA. It is proposed therefore that vanadium(IV) species of the type (L1VR)-R-IV(AlR2Cl) and (L2VR)-R-IV(AlR2Cl) can be the active species (or their immediate precursors) of the catalyst system 1,2/AlR2Cl/ETA.

  DOI：

  10.1021/om900515h
• 作为产物：
  描述：

  氧化苯乙烯 、 以 四氢呋喃 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Castellano, Barbara, Inorganic Chemistry, 1999, vol. 38, # 14, p. 3406 - 3413

  摘要：

  DOI：