terbutylate samarium binaphtholate | 1165844-41-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: terbutylate samarium binaphtholate
• CAS: 1165844-41-6
• 化学式: C₂₄H₂₁O₃Sm
• 分子量: 507.789
• InChiKey: YXRCOXZWPOGTBL-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  potassium tert-butylate 、 SmI3(THF)3.5 、 (potassium)2(1,1'-binaphthyl-2,2'-diolate) 以 四氢呋喃 为溶剂， 以82%的产率得到terbutylate samarium binaphtholate
  参考文献：
  名称：

  Chiral samarium iodo and terbutylate derivatives as catalysts for MPV ketone reductions

  摘要：

  Samarium iodo and terbutylate derivatives coordinated by various chiral ligands have been prepared and used in situ as new catalysts for MPV reductions of aromatic ketones. The most active catalyst is samarium terbutylate binaphtolate albeit with moderate enantioselectivity. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.11.011