N-hydroxyethyl-3,4:9,10-perylenetetracarboxylic-3,4-anhydride-9,10-imide | 80689-49-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并吡喃类
• 英文名称: N-hydroxyethyl-3,4:9,10-perylenetetracarboxylic-3,4-anhydride-9,10-imide
• 英文别名: 18-(2-Hydroxyethyl)-7-oxa-18-azaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 80689-49-2
• 化学式: C₂₆H₁₃NO₆
• 分子量: 435.392
• InChiKey: GKTIEOHELPHQEO-UHFFFAOYSA-N

物化性质

• 熔点：
  >400 °C
• 沸点：
  782.3±40.0 °C(Predicted)
• 密度：
  1.691±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  33
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  101
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N-hydroxyethyl-3,4:9,10-perylenetetracarboxylic-3,4-anhydride-9,10-imide 在 aluminum (III) chloride 、 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 、 N-甲基吡咯烷酮 为溶剂， 反应 23.0h， 生成 2-[18-[[3,5-Bis(2-ethylhexoxy)phenyl]methyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaen-7-yl]ethanol
  参考文献：
  名称：

  Synthesis and spectral properties of perylene–rhodamine dyads with lipophilic dendritic auxiliaries

  摘要：

  The present publication reports a new entry of perylene-rhodamine dyads, whose solubilities in organic solvents are enhanced by the lipophilic dendritic auxiliaries. Spectroscopic studies on these dyad systems have demonstrated that the intramolecular Forster resonance energy transfer (FRET) from the perylene donor to the rhodamine acceptor was activated upon protonation with either H2SO4 or TFA to result in drastic colour change of the fluorescence emissions. This phenomenon can be reasonably accounted for in terms of the switching behaviour of the FRET interactions, which is suppressed by disruptive interference from lone pair electrons of the amino moieties. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2014.10.034
• 作为产物：
  描述：

  3,4,9,10-苝四羧酸二酐 在 potassium hydroxide 作用下， 以 水 为溶剂， 反应 12.5h， 生成 N-hydroxyethyl-3,4:9,10-perylenetetracarboxylic-3,4-anhydride-9,10-imide
  参考文献：
  名称：

  亲脂性双蒽蒽荧光团的合成：合成新型光采树枝状聚合物的多功能构建基块

  摘要：

  亲脂性基于双蒽的荧光团及其衍生物是通过9-蒽硼酸与取代的二溴苯的Suzuki-Miyaura交叉偶联反应合成的。除了理想的荧光特性外，由于它们的化学稳定性，这些分子系统还被证明是合成两种新型光采树枝状大分子的通用构建基块。

  DOI：

  10.1016/j.tet.2011.10.021

文献信息

• 一种石墨烯分散剂及其制备方法、应用
  申请人：浙江省海洋开发研究院

  公开号：CN108862264B

  公开（公告）日：2021-08-17

  本发明涉及石墨烯领域，公开了一种石墨烯分散剂及其制备方法、应用。本发明的石墨烯分散剂能够促进石墨烯分散，分散性能好，并且其能够与酸反应生成盐，在剥离后，能够用稀酸洗涤容易除去分散剂，避免分散剂对石墨烯性能的影响。
• Synthesis and Luminescence of POSS-Containing Perylene Bisimide-Bridged Amphiphilic Polymers
  作者：Fanfan Du、Jiao Tian、Hu Wang、Bin Liu、Bangkun Jin、Ruke Bai

  DOI：10.1021/ma300100s

  日期：2012.4.10

  A novel well-defined amphiphilic fluorescent polymer containing asymmetric perylene bisimide was designed and synthesized by combining reaction of perylene anhydride with amino functional polyhedral oligomeric silsesquioxane (POSS) and atom transfer radical polymerization (ATRP) of N-isopropylacrylamide (NIPAM). All the intermediate and final products were characterized by NMR, Fourier transform infrared spectroscopy (FT-IR), elemental analyses, and gel permeation chromatograph (GPC). Self-assembly of the amphiphilic polymers was investigated in aqueous solution and POSS-containing hybrid nanoparticles were obtained and characterized by dynamic laser light scattering (DLS) and transmission electron microscopy (TEM). The novel hybrid nanoparticles exhibit attractive high red fluorescence at 645 nm due to the significant effect of the bulky POSS moieties. Moreover, based on the thermoresponsive PNIPAM coronas, the fluorescence intensity of the self-assembled hybrid nanoparticles can be further enhanced and tuned by changing temperature.
• TROESTER, H., DYES AND PIGM., 1983, 4, N 3, 171-177
  作者：TROESTER, H.

  DOI：——

  日期：——