1,4,8,11,15,18-hexaheptyltribenzo[b,g,l]-25,28-etheno-23,23a,24,29,29a,30-octahydro-26,27-dimethylene-23,30-epoxytetraceno[q]porphyrinazinatonickel(II) | 197728-89-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 1,4,8,11,15,18-hexaheptyltribenzo[b,g,l]-25,28-etheno-23,23a,24,29,29a,30-octahydro-26,27-dimethylene-23,30-epoxytetraceno[q]porphyrinazinatonickel(II)
• CAS: 197728-89-5
• 化学式: C₉₀H₁₁₄N₈NiO
• 分子量: 1382.64
• InChiKey: XHVLEBZCBVDAPU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,4,8,11,15,18-hexaheptyltribenzo[b,g,l]-25,28-etheno-23,23a,24,29,29a,30-octahydro-26,27-dimethylene-23,30-epoxytetraceno[q]porphyrinazinatonickel(II) 、 足球烯 以 甲苯 为溶剂， 以62%的产率得到1,4,8,11,15,18-hexaheptyltribenzo[b,g,l]-27,28-(1,2-dihydrofullereno)-25,30-etheno-23,23a,24,25,26,29,30,31,31a,32-tetradecahydro-23,32-epoxypentaceno[q]porphyrinazinatonickel(II)
  参考文献：
  名称：

  [60]富勒烯与酞菁和半卟啉的Diels-Alder加合物的合成和电化学

  摘要：

  AbstractThe synthesis of a new Diels‐Alder adduct 7 of [60]fullerene and a phthalocyaninenickel compound containing a longer spacer than the originally reported Diels‐Alder adduct 1 is described. The bisenophilic hemiporphyrazinenickel compound 11 reacts with [60]fullerene to form a Diels‐Alder adduct 12 containing two fullerene units. Spectroelectrochemical investigations of 7 and 12 reveal multiple reductions, which are attributed to the corresponding subunits of the molecules. In contrast to 1, the election acceptor properties of the [60]fullerene unit in both molecules have no influence on the electronic properties of the phthalocyanine and hemiporphyrazine, respectively.

  DOI：

  10.1002/cber.19971301005
• 作为产物：
  描述：

  1,4,8,11,15,18-hexaheptyltribenzo[b,g,l]-23,26-dihydro-23,26-epoxynaphtho[q]porphyrinazinatonickel(II) 、 5,6,7,8-四(亚甲基)-双环[2.2.2]-2-辛烯 以 甲苯 为溶剂， 以79%的产率得到1,4,8,11,15,18-hexaheptyltribenzo[b,g,l]-25,28-etheno-23,23a,24,29,29a,30-octahydro-26,27-dimethylene-23,30-epoxytetraceno[q]porphyrinazinatonickel(II)
  参考文献：
  名称：

  [60]富勒烯与酞菁和半卟啉的Diels-Alder加合物的合成和电化学

  摘要：

  AbstractThe synthesis of a new Diels‐Alder adduct 7 of [60]fullerene and a phthalocyaninenickel compound containing a longer spacer than the originally reported Diels‐Alder adduct 1 is described. The bisenophilic hemiporphyrazinenickel compound 11 reacts with [60]fullerene to form a Diels‐Alder adduct 12 containing two fullerene units. Spectroelectrochemical investigations of 7 and 12 reveal multiple reductions, which are attributed to the corresponding subunits of the molecules. In contrast to 1, the election acceptor properties of the [60]fullerene unit in both molecules have no influence on the electronic properties of the phthalocyanine and hemiporphyrazine, respectively.

  DOI：

  10.1002/cber.19971301005