11-oxo-10,10a,11,16-tetrahydro-4bH-10a-aza-15b-azoniadibenzo[a,e]pleiadene perchlorate | 1132819-56-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 11-oxo-10,10a,11,16-tetrahydro-4bH-10a-aza-15b-azoniadibenzo[a,e]pleiadene perchlorate
• CAS: 1132819-56-7
• 化学式: C₂₄H₁₇N₂O*ClO₄
• 分子量: 448.862
• InChiKey: SJFHOFNDJCJLKY-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  11-oxo-10,10a,11,16-tetrahydro-4bH-10a-aza-15b-azoniadibenzo[a,e]pleiadene perchlorate 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 反应 0.25h， 以73%的产率得到10,11,15c,16-tetrahydro-10a,15b-diazadibenzo[a,e]pleiaden-11-ones
  参考文献：
  名称：

  缩合异喹啉28 *。10a，15b-二氮杂二苯并[a，e] -pleiaden-11-ones的合成及性能

  摘要：

  The reaction of 7,12-dihydro-5H-isoquino[2,3-a]quinazolin-5-ones with o-xylidene dibromide leads to 11-oxo-4bH,5H,10H,11H,16H-10a-aza-15b-azoniadibenzo[a,e]pleiadene bromides, which are converted to 11-oxo-10H,11H,16H-10a-aza-15b-azoniadibenzo[a,e]pleiadene salts upon oxidation using nitrobenzene. The reaction of these salts with benzylamine leads to 6-{2-[(benzylimino)methyl]phenyl}-7,12-dihydroisoquino[3,2-b][2]benzazepin-14(6H)-ones, which recyclize to 11-oxo-5H,10H,11H-10a-aza-15b-azoniadibenzo[a,e]pleiadene perchlorates upon the action of perchloric acid. The reactions of the 10a,15b-diazadibenzo[a,e]pleiadene salts obtained with NaBH4 were studied and the structures of the reduction products were determined by spectral methods.

  DOI：

  10.1007/s10593-008-0025-5
• 作为产物：
  描述：

  11-oxo-4a,5,10,16-tetrahydro-11H-10b-azonia-15b-azadibenz[a,e]pleiadene bromide 在 高氯酸 、 硝基苯 作用下， 以 水 为溶剂， 反应 0.17h， 以69%的产率得到11-oxo-10,10a,11,16-tetrahydro-4bH-10a-aza-15b-azoniadibenzo[a,e]pleiadene perchlorate
  参考文献：
  名称：

  缩合异喹啉28 *。10a，15b-二氮杂二苯并[a，e] -pleiaden-11-ones的合成及性能

  摘要：

  The reaction of 7,12-dihydro-5H-isoquino[2,3-a]quinazolin-5-ones with o-xylidene dibromide leads to 11-oxo-4bH,5H,10H,11H,16H-10a-aza-15b-azoniadibenzo[a,e]pleiadene bromides, which are converted to 11-oxo-10H,11H,16H-10a-aza-15b-azoniadibenzo[a,e]pleiadene salts upon oxidation using nitrobenzene. The reaction of these salts with benzylamine leads to 6-{2-[(benzylimino)methyl]phenyl}-7,12-dihydroisoquino[3,2-b][2]benzazepin-14(6H)-ones, which recyclize to 11-oxo-5H,10H,11H-10a-aza-15b-azoniadibenzo[a,e]pleiadene perchlorates upon the action of perchloric acid. The reactions of the 10a,15b-diazadibenzo[a,e]pleiadene salts obtained with NaBH4 were studied and the structures of the reduction products were determined by spectral methods.

  DOI：

  10.1007/s10593-008-0025-5