N,N'-dimethyl<(8-dimethylaminomethyl)naphthyl>phenylsila-2-imidazoline | 138767-61-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N,N'-dimethyl<(8-dimethylaminomethyl)naphthyl>phenylsila-2-imidazoline
• 英文别名: 1-[8-(1,3-dimethyl-2-phenyl-1,3,2-diazasilolidin-2-yl)naphthalen-1-yl]-N,N-dimethylmethanamine
• CAS: 138767-61-0
• 化学式: C₂₃H₂₉N₃Si
• 分子量: 375.589
• InChiKey: VLEAZSPPTPSALK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.34
• 重原子数：
  27.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  9.72
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  N,N'-dimethyl<(8-dimethylaminomethyl)naphthyl>phenylsila-2-imidazoline 在 二硫化碳 作用下， 反应 0.08h， 生成 <8-(dimethylaminomethyl)-1-naphthyl>phenylsilathione
  参考文献：
  名称：

  Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts

  摘要：

  Heteroorganic amidosilanes are readily obtained by interaction of CO2, CS2 and other heterocumulenes with pentacoordinated diaminosilanes. A comparison is made with the corresponding reactions of tetracoordinated species. Decomposition of these bifunctional organosilanes gives 2-substituted ureido derivatives and base-stabilized low coordinated silicon species, seemingly by a unimolecular thermal beta-elimination.

  DOI：

  10.1016/0022-328x(91)86160-r
• 作为产物：
  描述：

  (8-dimethylaminomethyl)naphthylphenyldifluorosilane 、 Li2(MeNCH2CH2NMe) 以 四氢呋喃 、 乙醚 为溶剂， 反应 24.0h， 生成 N,N'-dimethyl<(8-dimethylaminomethyl)naphthyl>phenylsila-2-imidazoline
  参考文献：
  名称：

  Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts

  摘要：

  Heteroorganic amidosilanes are readily obtained by interaction of CO2, CS2 and other heterocumulenes with pentacoordinated diaminosilanes. A comparison is made with the corresponding reactions of tetracoordinated species. Decomposition of these bifunctional organosilanes gives 2-substituted ureido derivatives and base-stabilized low coordinated silicon species, seemingly by a unimolecular thermal beta-elimination.

  DOI：

  10.1016/0022-328x(91)86160-r