bis(biphenyl-4-yl)[4'-(9-phenyl-9H-carbazol-3-yl)biphenyl-4-yl]amine | 1028648-66-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(biphenyl-4-yl)[4'-(9-phenyl-9H-carbazol-3-yl)biphenyl-4-yl]amine
• 英文别名: 4-phenyl-N-[4-[4-(9-phenylcarbazol-3-yl)phenyl]phenyl]-N-(4-phenylphenyl)aniline
• CAS: 1028648-66-9
• 化学式: C₅₄H₃₈N₂
• 分子量: 714.909
• InChiKey: KXKYUMCGWKJYSL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  56
• 可旋转键数：
  8
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-(4-溴苯基)-9-苯基咔唑 、 B-[4-[双(联苯-4-基)氨基]苯基]硼酸 在 palladium diacetate 、 三(邻甲基苯基)磷 potassium carbonate 作用下， 以 乙二醇二甲醚 、 水 为溶剂， 反应 5.0h， 以46%的产率得到bis(biphenyl-4-yl)[4'-(9-phenyl-9H-carbazol-3-yl)biphenyl-4-yl]amine
  参考文献：
  名称：

  [EN] CARBAZOLE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING CARBAZOLE DERIVATIVE
  [FR] DÉRIVÉ CARBAZOLE, ET ÉLÉMENT ÉMETTANT DE LA LUMIÈRE, DISPOSITIF ÉMETTANT DE LA LUMIÈRE, ET DISPOSITIF ÉLECTRONIQUE UTILISANT LE DÉRIVÉ CARBAZOLE

  摘要：

  为提供具有高发光效率的发光元件，并提供一种低功耗、低电压驱动的发光装置和电子设备，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3 和 α4 分别表示具有小于或等于 13 个碳原子的芳基基团；Ar1 和 Ar2 分别表示具有小于或等于 13 个碳原子的芳基基团；R1 表示氢原子、具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种；R2 表示具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种。此外，l、m 和 n 分别独立地为 0 或 1。

  公开号：

  WO2009072587A1

文献信息

• ORGANIC LIGHT EMITTING ELEMENT, DISPLAY DEVICE, IMAGE INFORMATION PROCESSING DEVICE, LIGHTING DEVICE, IMAGE FORMING DEVICE, EXPOSURE DEVICE, AND ORGANIC PHOTOELECTRIC CONVERSION ELEMENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20170012215A1

  公开（公告）日：2017-01-12

  The present disclosure provides an organic light emitting element which has a pair of electrodes and an organic compound layer disposed therebetween and in which the organic compound layer contains an organic compound represented by the following general formula [1], wherein in the formula [1], Ar 1 and Ar 2 each independently represent an aromatic hydrocarbon group or a heteroaromatic ring group, R 1 to R 4 are each independently selected from a hydrogen atom or a substituent, R 1 and R 2 and R 3 and R 4 each may form a benzene ring, wherein the benzene ring may have at least one substituent.

  本公开提供了一种有一对电极和位于其之间的有机化合物层的有机发光元件，其中所述有机化合物层包含由下述通用式[1]表示的有机化合物， 在通用式[1]中，Ar1和Ar2分别独立表示芳香烃基或杂芳环基，R1至R4分别独立地选自氢原子或取代基，R1和R2以及R3和R4各自可以形成苯环，其中苯环可以具有至少一个取代基。
• ORGANIC ELECTROLUMINESCENCE ELEMENT AND ELECTRONIC APPARATUS
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20210005826A1

  公开（公告）日：2021-01-07

  An organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises a first compound, a second compound having a hole mobility larger than that of the first compound, and a dopant material showing a fluorescent spectrum with a half width of 30 nm or less; and an organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises a first compound, a third compound having an affinity larger than that of the first compound, and a dopant material showing a fluorescent spectrum with a half width of 30 nm or less and the content of the third compound in the fluorescent emitting layer is less than that of the first compound in the fluorescent emitting layer are excellent in their performance.

  一种有机电致发光装置，包括阴极、阳极以及设置在阴极和阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括第一化合物、第二化合物和掺杂材料，所述第二化合物的空穴迁移率大于所述第一化合物，且所述掺杂材料显示的荧光光谱半宽为30纳米或更小；以及一种有机电致发光装置，包括阴极、阳极以及设置在阴极和阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括第一化合物、第三化合物和掺杂材料，所述第三化合物与所述第一化合物的亲和力更大，且所述掺杂材料显示的荧光光谱半宽为30纳米或更小，且所述第三化合物在荧光发射层中的含量小于所述第一化合物在荧光发射层中的含量，这些装置的性能都十分出色。
• ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20210005825A1

  公开（公告）日：2021-01-07

  An organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises at least one first compound selected from the compounds represented by formulae (19), (21), (22), and (23), a second compound selected from the compounds represented by formula (3a), and a dopant material selected from the compounds represented by formulae (D1) and (D2) is excellent in its performance.

  一个有机电致发光装置，包括阴极、阳极和位于阴极与阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括至少一种由公式（19）、（21）、（22）和（23）所表示的化合物中选择的第一化合物，一种由公式（3a）所表示的化合物中选择的第二化合物，以及一种由公式（D1）和（D2）所表示的化合物中选择的掺杂材料，其性能卓越。
• AROMATIC HETEROCYCLIC DERIVATIVE, AND ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATION DEVICE, AND DISPLAY DEVICE USING AROMATIC HETEROCYCLIC DERIVATIVE
  申请人：Konica Minolta, Inc.

  公开号：US20180037546A1

  公开（公告）日：2018-02-08

  The present invention addresses the problem of providing a novel aromatic heterocyclic derivative, providing an organic EL element that uses the derivative and has high luminous efficiency, long luminescence life, and few changes over time when used under high temperatures, and providing a display device and an illumination device that are equipped with the organic El element. This aromatic heterocyclic derivative is characterized by having a specific structure which includes a carbazole ring.

  本发明解决了提供一种新颖的芳香杂环衍生物的问题，提供了一种使用该衍生物并具有高发光效率、长发光寿命，在高温下使用时变化少的有机EL元件，并提供了配备有该有机EL元件的显示装置和照明装置。这种芳香杂环衍生物的特点在于具有包括一个咔唑环在内的特定结构。
• ORGANIC COMPOUND, ORGANIC LIGHT-EMITTING ELEMENT, DISPLAY APPARATUS, PHOTOELECTRIC CONVERSION APPARATUS, ELECTRONIC APPARATUS, LIGHTING APPARATUS, MOVING OBJECT, AND EXPOSURE LIGHT SOURCE
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20210070677A1

  公开（公告）日：2021-03-11

  An organic compound represented by formula [1] is provided. Ring A is a polycyclic aromatic hydrocarbon ring having a fluoranthene skeleton and having 16 to 60 carbon atoms and optionally has, as a substituent, a substituted or unsubstituted alkyl group or the like. Rings B 1 and B 2 are aromatic hydrocarbon rings having 6 to 18 carbon atoms and each have two or more electron withdrawing groups. Q 1 and Q 2 respectively represent one of the electron withdrawing groups of the ring B 1 and one of the electron withdrawing groups of the ring B 2 , and are respectively located at an ortho position of the ring B 1 and at an ortho position of the ring B 2 with respect to the ring A.

  提供了一个由化学式[1]表示的有机化合物。环A是一个具有芴骨架的多环芳烃环，含有16至60个碳原子，并且可选地具有取代或未取代的烷基基团等作为取代基。环B1和B2是具有6至18个碳原子的芳香烃环，每个环具有两个或更多的电子吸引基团。Q1和Q2分别表示环B1和环B2的一个电子吸引基团，并且分别位于环A相对于环B1的邻位和环B2的邻位。