bis-[2-(N-methyl-anilino)-ethyl]-disulfide | 739330-93-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis-[2-(N-methyl-anilino)-ethyl]-disulfide
• 英文别名: Bis-[2-(N-methyl-anilino)-aethyl]-disulfid；N,N'-(disulphanediyldiethane-2,1-diyl)bis(N-methylaniline)；N,N'-(disulfanediyldiethane-2,1-diyl)bis(N-methylaniline)；N-methyl-N-[2-[2-(N-methylanilino)ethyldisulfanyl]ethyl]aniline
• CAS: 739330-93-9
• 化学式: C₁₈H₂₄N₂S₂
• 分子量: 332.534
• InChiKey: PQLXUKKUZKLRFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  22
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  57.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis-[2-(N-methyl-anilino)-ethyl]-disulfide 在 sodium hydroxide 、 三氯氧磷 作用下， 以 二氯甲烷 、 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 4,4'-{disulphanediylbis[ethane-2,1-diyl-(methylimino)]}dibenzaldehyde
  参考文献：
  名称：

  Hair compositions comprising at least one disulfide direct dye and at least one alkaline hydroxide agent and simultaneous hair shaping an dyeing processes

  摘要：

  本文揭示了用于同时塑造、染色和/或漂白角蛋白纤维的组合物，包括至少一种二硫化物直接染料和至少一种有机或矿物质羟基碱性剂。本文还揭示了使用上述组合物进行角蛋白纤维的同时塑造、染色和/或漂白的过程，以及包含上述组合物的分隔式装置。本文所揭示的组合物可能使得能够获得持久的染色效果，同时限制角蛋白纤维的降解。

  公开号：

  US20090126755A1
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium disulfide 、 水 作用下， 生成 bis-[2-(N-methyl-anilino)-ethyl]-disulfide
  参考文献：
  名称：

  Kolesowa; Kissel, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 1084;engl.Ausg.S.1168

  摘要：

  DOI：

文献信息

• [EN] INDOLINIUM-DERIVED THIOL/DISULFIDE DYE, DYE COMPOSITION COMPRISNG THIS DYE, PROCESS FOR LIGHTENING KERATIN MATERIALS USING THIS DYE<br/>[FR] COLORANT THIOL/DISULFURE DÉRIVÉ D'INDOLIUM, COMPOSITION COLORANTE COMPRENANT LEDIT COLORANT, PROCÉDÉ D'ÉCLAIRCISSEMENT DE MATÉRIAUX À BASE DE KÉRATINE AU MOYEN DE CE COLORANT
  申请人：OREAL

  公开号：WO2009037348A1

  公开（公告）日：2009-03-26

  The invention relates to the dyeing of keratin materials using indolinium-derived thiol and disulfide fluorescent dyes. The invention relates to a dye composition comprising an indolinium-derived-chromophore thiol or disulfide dye and to a dyeing process with a lightening effect on keratin fibers such as the hair, using said composition. It similarly relates to novel indolinium-derived-chromophore thiol dyes and to the uses thereof in lightening keratin materials. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.

  该发明涉及使用吲哚啉衍生硫醇和二硫化物荧光染料对角蛋白材料进行染色。该发明涉及一种染料组合物，包括一种吲哚啉衍生色团硫醇或二硫化物染料，以及使用该组合物对角蛋白纤维（如头发）进行具有减淡效果的染色过程。它还涉及新型吲哚啉衍生色团硫醇染料及其在减淡角蛋白材料中的用途。该组合物能够实现一种具有减淡效果的染色，特别是在深色角蛋白纤维上表现出耐久性和可见性。
• HEMICYANIN STYRYL THIOL/DISULFIDE DYE, COMPOSITION COMPRISING HEMICYANIN STYRYL THIOL/DISULFIDE DYE, AND METHOD FOR LIGHTENING KERATIN MATERIALS USING HEMICYANIN STYRYL THIOL/DISULFIDE DYE
  申请人：GREAVES Andrew

  公开号：US20090211038A1

  公开（公告）日：2009-08-27

  The present disclosure relates to a novel dye composition for the dyeing and/or lightening of keratin materials, such dye comprising a hemicyanin styryl chromophore thiol or disulfide dye of formula (I) or (II): the organic or mineral acid salts thereof, optical isomers and geometric isomers thereof, and the solvates thereof such as hydrates. The present disclosure further relates to a dyeing process with a lightening effect on keratin materials, in particular keratin fibers, including human keratin fibers such as the hair, using said composition. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.

  本公开涉及一种用于染色和/或轻化角蛋白材料的新型染料组合物，所述染料包括式(I)或(II)的半氰靛基苯乙烯色团硫醇或二硫化物染料：其有机或矿物酸盐、其光学异构体和几何异构体，以及其溶剂化合物，如水合物。本公开还涉及一种对角蛋白材料，特别是角蛋白纤维，包括人类角蛋白纤维如头发，在使用所述组合物时具有轻化效果的染色过程。该组合物能够获得一种特别耐用且在深色角蛋白纤维上可见的具有轻化效果的染色。
• METHOD OF DYEING AND LIGHTENING KERATIN MATERIALS IN THE PRESENCE OF A REDUCING AGENT COMPRISING A FLUORESCENT DISULPHIDE DYE
  申请人：Daubresse Nicolas

  公开号：US20090313769A1

  公开（公告）日：2009-12-24

  The invention relates to a dyeing composition comprising a fluorescent disulphide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulphide dyes and to their uses in the lightening of keratin materials. This composition allows a particularly persistent lightening effect to be obtained.

  该发明涉及一种染料组合物，包括荧光二硫化物染料，以及使用该组合物进行具有漂白效果的角蛋白材料染色的方法。它还涉及新的荧光二硫化物染料及其在角蛋白材料漂白中的用途。该组合物可使得特别持久的漂白效果得以获得。
• METHOD OF COLOURING AND LIGHTENING KERATIN MATERIALS IN THE PRESENCE OF A REDUCING AGENT COMPRISING A FLUORESCENT DISULPHIDE DYE
  申请人：Daubresse Nicolas

  公开号：US20120177587A1

  公开（公告）日：2012-07-12

  The invention relates to a dyeing composition comprising a fluorescent disulphide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulphide dyes and to their uses in the lightening of keratin materials. This composition allows a particularly persistent lightening effect to be obtained.

  该发明涉及一种染料组合物，包括荧光二硫化物染料，以及一种使用该组合物进行具有减淡效果的角蛋白材料染色的方法。它还涉及新的荧光二硫化物染料及其在角蛋白材料减淡方面的应用。该组合物可使得得到一种特别持久的减淡效果。
• METHOD OF DYEING AND LIGHTENING KERATIN MATERIALS IN THE PRESENCE OF A REDUCING AGENT COMPRISING A FLUORESCENT DEISULPHIDE DYE
  申请人：L'OREAL

  公开号：US20140033450A1

  公开（公告）日：2014-02-06

  The invention relates to a dyeing composition comprising a fluorescent disulphide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulphide dyes and to their uses in the lightening of keratin materials. This composition allows a particularly persistent lightening effect to be obtained.

  本发明涉及一种染料组合物，其包括荧光二硫化物染料，并涉及一种使用该组合物进行具有减轻效果的角蛋白材料染色的方法。本发明还涉及新的荧光二硫化物染料及其在角蛋白材料减轻中的用途。该组合物可使得减轻效果尤为持久。