2,7-bis(methacryloyloxy)naphthalene | 42980-04-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,7-bis(methacryloyloxy)naphthalene
• 英文别名: 2,7-Naphthylendimethacrylat；2,7-Dimethacryloxynapthalene；[7-(2-methylprop-2-enoyloxy)naphthalen-2-yl] 2-methylprop-2-enoate
• CAS: 42980-04-1
• 化学式: C₁₈H₁₆O₄
• 分子量: 296.323
• InChiKey: QIZFFCBKBCNWAY-UHFFFAOYSA-N

物化性质

• 密度：
  1.163±0.06 g/cm3 (20 ºC 760 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,7-二羟基萘 、 甲基丙烯酸酐 、 甲基丙烯酸 、 碳酸氢钠 在 4-二甲氨基吡啶 magnesium sulfate 、 甲苯 作用下， 以 水 、 甲苯 为溶剂， 反应 72.0h， 以25.1 g (84.7% of theoretical yield) of what的产率得到2,7-bis(methacryloyloxy)naphthalene
  参考文献：
  名称：

  Curatives for epoxy compositions

  摘要：

  本发明提供了环氧和氧杂环戊烷组合物，其中包括本文所描述的新型酰氧基和N-酰基固化剂。使用本发明的固化剂可使固化粘合剂组合物的粘附性显著增加，并且与使用其他类型固化剂固化的树脂相比，其亲水性降低。此外，本发明的固化剂不会干扰自由基固化，因此适用于混合固化热固性组合物的使用。

  公开号：

  US08431655B2

文献信息

• CURATIVES FOR EPOXY ADHESIVE COMPOSITIONS
  申请人：Dershem Stephen M.

  公开号：US20100113643A1

  公开（公告）日：2010-05-06

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  该发明提供了包括新型酰氧基和N-酰基固化剂的环氧树脂和氧环烷组合物。使用该发明的固化剂可使胶粘剂组合物固化后的粘附性大大增加，并且与用其他类型的固化剂固化的树脂相比，其亲水性减少。此外，该发明的固化剂不会干扰自由基固化，因此适用于混合固化热固性组合物的使用。
• POLYMERIZABLE COMPOUND AND LIQUID CRYSTAL COMPOSITION INCLUDING IT
  申请人：Ito Maiko

  公开号：US20120092608A1

  公开（公告）日：2012-04-19

  Provided is a polymerizable compound with large solubility in a liquid crystal composition and high reactivity irradiated by ultraviolet in the longer wavelength range. Provided is a liquid crystal composition that satisfies at least one of characteristics such as high maximum temperature of a nematic phase, low minimum temperature of a nematic phase, small viscosity, suitable optical anisotropy, large negative dielectric anisotropy, large specific resistance, high stability to ultraviolet light and high stability to heat, or that is suitably balanced between at least two of the characteristics. Provided is the polymerizable compound wherein at least one of a 1,3-phenylene structure and a 2,7-fluorenediyl structure is introduced to the polymerizable compound to give stable displays by forming a polymer with a high degree of polymerization in a PSA device production process using longer wavelengths, the liquid crystal composition includes the compound, and the liquid crystal display device contains the composition.

  提供了一种具有较大溶解度和高反应性的聚合物化合物，该化合物可在较长波长范围内受紫外线照射。提供了一种液晶组合物，该组合物具有以下特征之一：高向列相最高温度、低向列相最低温度、小粘度、适当的光学各向异性、大负介电各向异性、大特定电阻、对紫外线和热稳定性高，或在至少两个特征之间适当平衡。提供了一种聚合物化合物，其中至少引入了1,3-苯基结构和2,7-芴基二基结构，以在使用较长波长的PSA设备生产过程中形成高聚物，从而提供稳定的显示，该液晶组合物包括该化合物，且液晶显示装置包含该组合物。
• CURATIVES FOR EPOXY COMPOSITIONS
  申请人：Dershem Stephen M.

  公开号：US20100249276A1

  公开（公告）日：2010-09-30

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  本发明提供了环氧和氧杂环烷组分，包括本文所述的新型酰氧基和N-酰基固化剂。使用本发明的固化剂可使固化的粘合剂组分具有显著增强的粘附性和降低的亲水性，与使用其他类型固化剂固化的树脂相比。此外，本发明的固化剂不干扰自由基固化，因此适用于混合固化热固性组分的使用。
• Curatives for epoxy compositions
  申请人：Dershem Stephen M

  公开号：US08431655B2

  公开（公告）日：2013-04-30

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  本发明提供了环氧和氧杂环戊烷组合物，其中包括本文所描述的新型酰氧基和N-酰基固化剂。使用本发明的固化剂可使固化粘合剂组合物的粘附性显著增加，并且与使用其他类型固化剂固化的树脂相比，其亲水性降低。此外，本发明的固化剂不会干扰自由基固化，因此适用于混合固化热固性组合物的使用。
• CROSSLINKABLE RESIN MOLDED BODY, CROSSLINKED RESIN MOLDED BODY, AND LAMINATE
  申请人：Zeon Corporation

  公开号：EP2653501A1

  公开（公告）日：2013-10-23

  A cross-linkable resin shaped article which contains a heat curable resin, cross-linking agent, and condensed aromatic polycyclic compound which has a (meth)acryloyloxy group, a cross-linked resin shaped article which is comprised of that cross-linkable resin shaped article which is cross-linked, and a laminate which is obtained by using these are provided. The cross-linkable resin shaped article and cross-linked resin shaped article of the present invention are excellent in heat resistance and further are useful in production of a low linear expansion laminate.

  本发明提供了一种含有热固化树脂、交联剂和具有（甲基）丙烯酰氧基的缩合芳香族多环化合物的可交联树脂成型品，一种由该可交联树脂成型品交联而成的交联树脂成型品，以及一种通过使用这些成型品获得的层压板。本发明的可交联树脂成型品和交联树脂成型品具有优异的耐热性，并可用于生产低线膨胀层压板。