9,10-bis(4-methyl-4'-bromo-diphenylamino)anthracene | 852535-46-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 9,10-bis(4-methyl-4'-bromo-diphenylamino)anthracene
• 英文别名: 9-N,10-N-bis(4-bromophenyl)-9-N,10-N-bis(4-methylphenyl)anthracene-9,10-diamine
• CAS: 852535-46-7
• 化学式: C₄₀H₃₀Br₂N₂
• 分子量: 698.5
• InChiKey: KPDISFFJVJTSNC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  44
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9,10-bis(4-methyldiphenylamino)anthracene 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 DMF (N,N-dimethyl-formamide) 、 氯苯 为溶剂， 反应 1.0h， 生成 9,10-bis(4-methyl-4'-bromo-diphenylamino)anthracene
  参考文献：
  名称：

  [EN] HALOGENATED BISDIARYLAMINOPOLYCYLIC AROMATIC COMPOUNDS AND POLYMERS THEREOF
  [FR] COMPOSES AROMATIQUES POLYCYCLIQUES BISDIARYLAMINO HALOGENES ET LEURS POLYMERES

  摘要：

  描述了一种卤代双二芳胺多环芳香化合物，以及由此制成的聚合物和使用这些聚合物的聚合物发光二极管器件。卤代化合物由式(I)表示，其中Ar和Ar'分别是取代或未取代的芳基，Z是多环芳基，其中至少一个Ar'基团是卤代芳基。使用从该卤代化合物制备的聚合物的器件表现出改善的性能和更长的寿命，可能是由于聚合物骨架中存在几何约束的双芳胺多环芳香基团。

  公开号：

  WO2005049546A1

文献信息

• POLYMER COMPOUND AND POLYMER LIGHT-EMITTING DEVICE
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2048176A1

  公开（公告）日：2009-04-15

  A polymer compound comprising repeating units of the following formulae (I), (II) and (III): (wherein, R1 and R2 represent a hydrogen atom, alkyl group, alkoxy group or the like, R3 and R4 represent an alkyl group, alkoxy group or the like, and a and b represent 0 to 3, and the like.) (wherein, RN1 represents an alkyl group, R5 and R6 represent an alkyl group, alkoxy group or the like, and c and d represent 0 to 3.)         (̵Ar)̵     (III) (wherein, Ar represents a divalent condensed polycyclic hydrocarbon group or the like.).

  由下式（I）、（II）和（III）的重复单元组成的聚合物化合物： (其中，R1 和 R2 代表氢原子、烷基、烷氧基或类似基团，R3 和 R4 代表烷基、烷氧基或类似基团，a 和 b 代表 0 至 3 或类似基团）。 (其中，RN1 代表烷基，R5 和 R6 代表烷基、烷氧基或类似物，c 和 d 代表 0 至 3）。 (̵Ar)̵ (III) (其中，Ar 代表二价缩合多环烃基或类似基团）。
• METHOD FOR MANUFACTURING CHEMICAL COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3037398A1

  公开（公告）日：2016-06-29

  A method for producing a compound, comprising mixing a compound (1) having one or two leaving groups, a compound (2) having one or two boron atom-containing leaving groups, an organic base (P), and at least one selected from the group consisting of a phase transfer catalyst and an organic base (Q) larger in the number of carbon atoms than the above-mentioned organic base in the presence of a transition metal catalyst, thereby performing a coupling reaction between the above-mentioned compound (1) and the above-mentioned compound (2).

  一种生产化合物的方法，包括在过渡金属催化剂存在下，将具有一个或两个离去基团的化合物（1）、具有一个或两个含硼原子离去基团的化合物（2）、有机碱（P）和至少一种选自相转移催化剂和碳原子数大于上述有机碱的有机碱（Q）组成的组中的一种混合，从而在上述化合物（1）和上述化合物（2）之间进行偶联反应。
• PYRENE POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：Fukushima Daisuke

  公开号：US20100109517A1

  公开（公告）日：2010-05-06

  A polymer compound comprising a constitutional unit of the formula (1), and a repeating unit of any of the formulae (2) to (4): (wherein, x3, y1, y2, z1 to z3 are 0 or 1. y3 represents an integer of 0 to 2. u represents an integer of 0 to 8. Z represents a pyrene residue, Ar 1 represents an arylene group or di-valent heterocyclic group, and Ar 2 represents an aryl group or mono-valent heterocyclic group.)
• Polymeric compound and polymeric electroluminescence element using the same
  申请人：Fukushima Daisuke

  公开号：US20100176377A1

  公开（公告）日：2010-07-15

  A polymer compound comprising at least one of repeating units of the following formula (1) and at least one of repeating units selected from the following formulae (2) and (3). (Ar 1 represents an aryl group or monovalent aromatic heterocyclic group, Ar 2 represents an arylene group or divalent aromatic heterocyclic group, and Z represents a divalent aromatic group having a condensed ring structure.) (a ring A and a ring B represent an aromatic hydrocarbon ring, at least one of the ring A and the ring B is an aromatic hydrocarbon ring having two or more benzene rings condensed, and Rw and Rx represent each independently a hydrogen atom, alkyl group or the like.) (a ring C and a ring D represent an aromatic ring, Y represents an oxygen atom, sulfur atom or —O—C(R K ) 2 —, and R K represents a hydrogen atom, alkyl group or the like.).
• POLYMER COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：Mizuki Yumiko

  公开号：US20100259163A1

  公开（公告）日：2010-10-14

  Provided are a high polymer compound comprising a repeating unit having a function of a dopant and a repeating unit having a function of a host, a material for organic electroluminescence containing the above high polymer compound and an organic electroluminescence device comprising an anode, a cathode and an organic compound layer comprising a layer interposed between the anode and the cathode, wherein a layer of the above organic compound layers is a light emitting layer, and the organic compound layer contains the material for organic electroluminescence described above. The above high polymer compound is useful as a light emitting material and can achieve a high polymer EL device which is excellent in device characteristics such as a lifetime, a luminous efficiency and the like.