[NBu4][Pt(C6F5)3(7,8-benzo[h]quinoline)] | 181645-31-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [NBu4][Pt(C6F5)3(7,8-benzo[h]quinoline)]
• 英文别名: [NBu4][Pt(C6F5)3(7,8-benzoquinoline)]
• CAS: 181645-31-8
• 化学式: C₁₆H₃₆N*C₃₁H₉F₁₅NPt
• 分子量: 1117.94
• InChiKey: FBDKUKYLAKDABF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [NBu4][Pt(C6F5)3(7,8-benzo[h]quinoline)] 以 1,2-二氯乙烷 为溶剂， 以63%的产率得到(NBu₄)[Pt(bzq)(C₆F₅)₂]
  参考文献：
  名称：

  具有Pt-Cd键的五氟苯基配合物的合成，表征和光学性质

  摘要：

  新颖的双金属中性[（C 6 ˚F 5）4 PTCD（环烯）]和[（C 6 ˚F 5）2（C⋮CPH）2 PTCD（环烯）]（1，2）和阳离子[（C 6 ˚F 5）2（bzq）PtCd（cycln）]（ClO 4）（3）通过处理适当的阴离子起始前体[Pt（C 6 F 5）2 X 2 ] n制备了五氟苯基铂（II）-镉（II）衍生物-（n＝ 2，X ＝ C 6 F 5，C ＝ CPh；n＝ 1，X 2＝ bzq），具有Cd（ClO 4）2和循环。上的复合物的X射线衍射研究1，2，和3显示，它们是由一个短的Pt→镉施主受主键稳定化，此外，在复杂的2 CD的中心也被协调到C α两个炔基中的一个的组。相反，双核化合物[NBu 4 ] 2 [Pt 2（μ-Cl）2（C 6 F 5）4 ]与[Cd（cycln）（MeOH）2 ]（ClO 4）2给出四核衍生物[Pt（C 6 F 5）2 Cl（μ-Cl）Cd（cycln）]

  DOI：

  10.1021/om049719w
• 作为产物：
  描述：

  7,8-苯并喹啉 、 [NBu4]2[Pt2(μ-pentafluorophenyl)2(pentafluorophenyl)4] 以 二氯甲烷 为溶剂， 生成 [NBu4][Pt(C6F5)3(7,8-benzo[h]quinoline)]
  参考文献：
  名称：

  Pentafluorophenyl Complexes of Platinum Containing Intramolecular Pt···H Hydrogen Bridging Interactions. Crystal Structures of [NBu₄][Pt(C₆F₅)₃(8-hydroxyquinaldine)] and [NBu₄][Pt(C₆F₅)₃(8-methylquinoline)]

  摘要：

  Anionic complexes with the molecular formula [NBu(4)][Pt(C6F5)(3)L] (L = 8-hydroxyquinoline, C9H7NO, (1); 8-hydroxyquinaldine, C10H10NO, (2); 7,8-benzo[h]quinoline, C13H9N, (3); 8-methylquinoline, C10H9N (4)) were prepared by cleavage of the pentafluorophenyl bridging system in [NBu(4)](2)[Pt-2(mu-C6F5)(2)(C6F5)(4)] with L (1-4) or by substitution of the chloride ion by the ligand L in [NBu(4)](2)[Pt(C6F5)(3)L] (1 and 4). H-1 NMR spectra of 1-3 show the presence of a Pt ... H interaction in solution with J(Pt,H) of 69 (1), 88 (2), and 22 Hz (3). For 4, no Pt-H coupling is observed. Structures of complexes 2 and 4 were determined by single crystal X-ray diffraction. For 2 a Pt-H distance of 2.19 Angstrom was determined, whereas for 4 the methyl hydrogen atoms were not located and a Pt-H distance in the range of 2.3-2.6 Angstrom was calculated geometrically. Compound 2 (C44H45F15N2OPt) crystallizes in the monoclinic system, space group P2(1)/c: a = 18.376(6) Angstrom, b = 11.786(4) Angstrom, c = 20.473(7) Angstrom, beta = 102.88(6)degrees, V = 4322(3) Angstrom(3), Z = 4. Compound 4 (C44H45F15N2Pt) crystallizes in the triclinic system, space group P (1) over bar a = 12.125(2) Angstrom, b = 13.152(2) Angstrom, c = 14.795(7) Angstrom, alpha = 88.20(3)degrees, beta = 68.15(3)degrees, gamma = 86.37(1)degrees, V = 2185.2(5) Angstrom(3), Z = 2. The existence and nature of the Pt ... H interactions both in solution and in the solid state are discussed.

  DOI：

  10.1021/ic960118+