4-Chloro-2-[3-[3-[(5-chloro-2-hydroxyphenyl)methylideneamino]propylamino]propyliminomethyl]phenol | 294628-84-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-Chloro-2-[3-[3-[(5-chloro-2-hydroxyphenyl)methylideneamino]propylamino]propyliminomethyl]phenol
• CAS: 294628-84-5
• 化学式: C₂₀H₂₃Cl₂N₃O₂
• 分子量: 408.328
• InChiKey: YYAUHFMSUANIQP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  27
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  77.2
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-Chloro-2-[3-[3-[(5-chloro-2-hydroxyphenyl)methylideneamino]propylamino]propyliminomethyl]phenol 在 Et₃N 作用下， 以 甲醇 为溶剂， 生成 Fe(N,N'-bis(2-oxy-5-chlorobenzyliden)-1,7-diamino-4-azaheptane)(pyridine)BPh4
  参考文献：
  名称：

  具有五齿席夫碱配体的单核和双核铁（III）配合物的自旋交叉

  摘要：

  一系列单核六配位的铁（Ⅲ）配合物的，的[Fe（ ）（PY）] BPH 4，和双核六配位的铁（III）络合物，[（ ）的Fe（μ 2 -bpy）的Fe（）]（BPH 4）2，已制备，并对其磁性进行了研究；五齿配体是＝ saldptn ＝ N，N′-双（2-羟基亚苄基）-1，7-二氨基-4-氮杂庚烷的衍生物。它们的有效磁矩的温度变化表明发生了从低自旋态到高自旋态的自旋跃迁。磁数据被拟合为适用于单核和双核系统的类似于Ising的模型。

  DOI：

  10.1016/s0009-2614(00)00701-6

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: U: SVol.E2, 1.7.5, page 60 - 104
  作者：

  DOI：——

  日期：——
• Single site anchored novel Cu(II) catalysts for selective liquid–gas phase O2 oxidation of n-alkanes
  作者：Gopal S. Mishra、Anil Kumar、Pedro B. Tavares

  DOI：10.1016/j.molcata.2012.01.030

  日期：2012.5

  The pentacoordinate schiff-base trialkoxysilane Cu(II) complexes, i.e. Cu[Sal(PMeOSi)DPTA], (III-a) and Cu[Cl-Sal(PMeOSi)DPTA], (III-b) were synthesized and covalently anchored on SiO2 and Al2O3 matrixes as supported hybrid catalysts (i.e. III-a/SiO2 as Catal.-1, III-b/SiO2 as Catal.-2, III-a/Al2O3 as Catal.-3 and III-b/Al2O3 as Catal.-4). The characterization of supported Cu(II) complexes were performed with SEM-EDX, TGA,ICP, FT-IR and EPR analysis. Catalytic tests were conducted in the oxidation (O-2) of n-alkanes under relatively mild conditions, in a batch rocking type reactor. Remarkable high catalytic TONs, from 1468 up to 2422, were observed. Catal.-2 provided the best overall yield, 25.2% with 92% selectivity for n-hexane and 20.1% with 75% selectivity for n-heptane. A 20% improvement in the yields was obtained with PCA as co-catalyst. The impact of both C- and O- centred radical traps were also assessed in order to establish a radical mechanism. (C) 2012 Elsevier B.V. All rights reserved.
• Seven-co-ordinate uranyl compounds with planar quinquedentate [N3O2] salicylaldiminato ligands
  作者：E.D. McKenzie、R.E. Paine、S.J. Selvey

  DOI：10.1016/s0020-1693(00)86706-7

  日期：1974.1
• Single site anchored novel pentacoordinate Schiff-base Co(II) complexes over SBA-15 for selective oxidation (O2) of n-alkanes and kinetic study
  作者：Kelly Machado、Pedro B. Tavares、Cristina Freire、Gopal S. Mishra

  DOI：10.1016/j.poly.2013.11.025

  日期：2014.2

  Trimethoxysilane pentacoordinate Schiff-base Co-(II) complexes, i.e. Co[Cl-Sal(PMeO-Si)DPTA], (3.a) and Co[F-Sal(PMeO-Si)DPTA], (3.b) and Co[FCl-Sal(PMeO-Si)DPTA], (3.c) (DPTA = bis(aminopropyl)amine, Sal = salicylaldehyde) were synthesized and anchored into SBA-15 matrix to obtain novel supported hybrid catalysts. The catalysts were characterized by FT-IR, TEM, SEM, XRD, TG and BET analysis. These supported complex catalysts were tested in the catalytic oxidation of n-hexane and n-heptane with O-2 under relatively mild and solvent free conditions. A high TON of 3320 with 19.6% yield for n-hexane oxidation and a high TON of 3180 with 17.3% yield for n-heptane oxidation were obtained with 3.b anchored over SBA-15. The oxidation product regioselectivities were obtained as C-1(1):C-2(9.2):C-3(10.7) for n-hexane and C-1(1):C-2(9.0):C-3(9.7):C-4(2.7) for n-heptane. The reaction of kinetics follows a pseudo first-order reaction for both n-alkanes. Enhanced yields (30.6% for n-hexane oxidation and 23.8% for n-heptane oxidation) were obtained with the addition of PCA (pyrazinecarboxylic acid); the catalytic results of reactions made in the presence of radical traps suggested that the catalytic oxidation of n-hexane and n-heptane proceeded via free radicals. The catalyst recycles tests showed that it could be reused up to 7th catalytic cycles. (C) 2013 Elsevier Ltd. All rights reserved.