Deuteriosulfanium | 860222-86-2

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• 英文名称: Deuteriosulfanium
• CAS: 860222-86-2
• 化学式: H₃S
• 分子量: 36.0819
• InChiKey: RWSOTUBLDIXVET-DYCDLGHISA-O

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  1
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Deuteriosulfanium 、 氘代氟硫酸 、 五氟化锑 以 二氧化硫 为溶剂， 生成
  参考文献：
  名称：

  四氢ulf盐H4S2 +：氟硫酸中的硫化氢（DH2S +）的氢-氘交换-d：五氟化锑和氟硫酸：硫化五氢中的硫化氢（D2HS +）和理论计算

  摘要：

  DOI：

  10.1021/j100315a005
• 作为产物：
  描述：

  hydrogen sulfide cation 、 甲烷-D4 生成 Deuteriosulfanium
  参考文献：
  名称：

  Ion-molecule reactions in mixture of methane with water, hydrogen sulfide, and ammonia

  摘要：

  DOI：

  10.1021/ja00794a001

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.4a/b, 1.3.8.11.2, page 214 - 216
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.4a/b, 1.3.8.11.1, page 212 - 214
  作者：

  DOI：——

  日期：——
• Ion—Molecule Reactions of Propane Ions with Benzene, 1,3—Butadiene, Hydrogen Sulfide, and Nitric Oxide
  作者：L. I. Bone、J. H. Futrell

  DOI：10.1063/1.1701638

  日期：1967.12

  Reactions of the principal primary ions from propane, C3H8+, C3H7+, C3H6+, C3H5+, C3H3+, C2H5+, C2H4+, C2H3+, and CH3+ with benzene, 1,3-butadiene, nitric oxide, and H2S were investigated in a tandem mass spectrometer. Reaction mechanisms are deduced for these systems and it is suggested that a relatively long-lived reaction complex is involved for most of these reactions. For the reaction of propyl ions with benzene an unstable adduct C9H13+ was observed which could be stabilized by collision and a unimolecular rate constant of 107sec−1 for its decomposition was estimated from its pressure dependence. In the H2S+–C3D8 and C3D8+—H2S systems charge exchange and deuteronation of H2S are competitive reactions, both proceeding via a long-lived intermediate C3D8H2S+ in which extensive isotopic exchange occurs. The results of this study are correlated with recent radiolysis experiments and it is concluded that these two methods for studing gas-phase ionic reactions are complementary.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.4a/b, 5.2.3, page 474 - 478
  作者：

  DOI：——

  日期：——
• Reactions of Gaseous Ions. V. Methane-Hydrogen Chloride and Methane-Hydrogen Sulfide
  作者：F. H. Field、F. W. Lampe

  DOI：10.1021/ja01554a001

  日期：1958.11