| 136952-01-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 136952-01-7；430430-07-2
• 化学式: C₁₀H₂₂Cl₄N₂O₂Pt
• 分子量: 539.189
• InChiKey: WCJTZRLBGVZDLR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 (二氯碘)-苯 以 氯仿 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  Imino-ether complexes of platinum: cis-[PtCl2(NHC(OR)Me)2] and [PtCl4(NHC(OR)Me)2], where R = Me, Et and Pri. Preparation, characterization and X-ray structure for [PtCl4(NHC(OPri)Me)2]2

  摘要：

  The reaction of cis-PtCl2(NCMe)2 with KOH or KOPh in MeOH, EtOH or Pr(i)OH produces the imino-ether complexes [PtCl2(NH = C(OR)Me)2] which have been characterized by IR, NMR and elemental analysis. The crystal structure of [PtCl2(NH = C(OPr(i))Me)2]2 was determined by X-ray diffraction. Each molecule comprises two units of [PtCl2(NH = C(OPr(i))Me)2] with a Pt---Pt distance of 3.327(1) angstrom. The lack of any bridging ligand suggests the presence of hydrogen bonds. The N(4)-Cl(3') and N(11)-Cl(2') distances are within the range of van der Waals' interactions. Oxidation reactions of these compounds with C6H5ICl2 give the corresponding platinum(IV) complexes [PtCl4(NH = C(OR)Me)2].

  DOI：

  10.1016/s0277-5387(00)86083-0