Vernonioside A₂ aglycone | 140923-30-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: Vernonioside A₂ aglycone
• CAS: 140923-30-4
• 化学式: C₂₉H₄₂O₅
• 分子量: 470.649
• InChiKey: RNJKMHGHSPMSHN-CZEFIVNTSA-N

反应信息

• 作为产物：
  描述：

  Vernonioside A3 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 反应 72.08h， 生成 Vernonioside A₂ aglycone
  参考文献：
  名称：

  Bitter steroid glucosides, vernoniosides A1, A2, and A3, and related B1 from a possible medicinal plant, Vernonia amygdalina, used by wild chimpanzees.

  摘要：

  From Vernonia amygdalina, a possible medicinal plant used by wild chimpanzees, three bitter steroid glucosides, vernoniosides A1,A2 and A3 and a nonbitter vernonioside B1, were isoluted. The oxygenation patterns of the aglycone parts were new, especially the pattern of the carboxyl group at C21. The oxygen functionalities at C16 were important for the bitter taste.

  DOI：

  10.1016/s0040-4020(01)88123-0