1-[9-fluorenyl-(CH2)2]-3-(2,6-Pr(i)2C6H3)-imidazol-2-ylidene-Ag-Br | 882302-71-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 1-[9-fluorenyl-(CH2)2]-3-(2,6-Pr(i)2C6H3)-imidazol-2-ylidene-Ag-Br
• CAS: 882302-71-8
• 化学式: Ag*Br*C₃₀H₃₂N₂
• 分子量: 608.37
• InChiKey: FFPAREKCNMVINJ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  K-1-[9-fluorenyl-(CH2)2]-3-(2,6-Pr(i)2C6H3)-imidazol-2-ylidene 、 silver(l) oxide 以 二氯甲烷 为溶剂， 以99%的产率得到1-[9-fluorenyl-(CH2)2]-3-(2,6-Pr(i)2C6H3)-imidazol-2-ylidene-Ag-Br
  参考文献：
  名称：

  Indenyl- and Fluorenyl-Functionalized N-Heterocyclic Carbene Complexes of Titanium and Vanadium

  摘要：

  The new N-heterocyclic carbene ligands functionalized with indenyl and fluorenyl groups, 1-[ind-(CH2)(2)]-NHC, (Ind-NHC)(-), and 1-[fl-(CH2)(2)]-NHC, (Fl-NHC)(-), where ind = 1-indenyl, fl = 9-fluorenyl, NHC = 3-DiPP-imidazol-2-ylidene, DiPP = 2,6-Pr-2(i)-C6H3, serve as versatile building blocks of Ti(III) and V(III) complexes.

  DOI：

  10.1021/om051017z