1,2-bis(2-formyl naphthoxy methyl)benzene | 1428631-42-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2-bis(2-formyl naphthoxy methyl)benzene
• CAS: 1428631-42-8
• 化学式: C₃₀H₂₂O₄
• 分子量: 446.502
• InChiKey: IORSKDKABAZQDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.78
• 重原子数：
  34.0
• 可旋转键数：
  8.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  52.6
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  1,2-bis(2-formyl naphthoxy methyl)benzene 、 二乙烯三胺 以 甲醇 为溶剂， 反应 48.0h， 生成
  参考文献：
  名称：

  A novel fluorescent nano-chemosensor for Al(III) ions using a new macrocyclic receptor

  摘要：

  A novel macrocyclic chemosensor (L) has been synthesized and characterized by common spectroscopic methods. Spectral properties of fluorescent macrocycle L were studied either as solution in ethanol or as insoluble nanoparticles in aqueous buffer solution. The nano-chemosensors with size about 35nm were prepared by nanoprecipitation method. The influence of metal cations such as Na(+), K(+), Cs(+), Mg(2+), Ba(2+), Al(3+), Pb(2+), Cr(3+), Mn(2+), Fe(3+), Fe(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Hg(2+) and Ag(+) on the spectroscopic properties of nano-chemosensor (L) in aqueous buffer solution were investigated by means of emission spectrophotometry. The macrocycle was found to be as an effective fluorescence sensor for Al(3+) ions.

  DOI：

  10.1016/j.saa.2014.01.015
• 作为产物：
  描述：

  1,2-二(溴甲基)苯 、 2-羟基-1-萘甲醛 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 48.0h， 以72%的产率得到1,2-bis(2-formyl naphthoxy methyl)benzene
  参考文献：
  名称：

  Co纳米颗粒上负载的新型Schiff碱Mn（III）和Co（II）配合物作为醇氧化的有效且可回收的磁性纳米催化剂

  摘要：

  在这项研究中，通过将锰和钴席夫碱配合物固定在钴磁铁矿纳米粒子（MNP）上，开发了两种高效且高度选择性的非均相催化剂。首先，Co @ SiO2核壳...

  DOI：

  10.1039/c6ra15967b

文献信息

• A novel cubic Zn‐citric acid‐based MOF as a highly efficient and reusable catalyst for the synthesis of pyranopyrazoles and 5‐substituted 1H‐tetrazoles
  作者：Mostafa Koolivand、Mohsen Nikoorazm、Arash Ghorbani‐Choghamarani、Masoud Mohammadi

  DOI：10.1002/aoc.6656

  日期：2022.6

  citric acid. To produce a novel Zn-based MOF catalyst, Zn ions were coordinated with the ligand functional groups that can be regarded as an alpha-hydroxy acid containing three carboxylic acids (COOH) and one hydroxyl (OH) group attached to the three-carbon skeleton. It was found that the Zn-CA-MOFs compound can participate as a catalyst in the synthesis of 5-substituted 1H-tetrazole and pyranopyrazole

  通过硝酸锌与柠檬酸的水热反应成功制备了一种高度稳定、高效的多相催化剂。为了生产一种新型的锌基 MOF 催化剂，锌离子与配体官能团配位，配体官能团可被视为含有三个羧酸 (COOH) 和一个羟基 (OH) 基团连接到三碳骨架上的 α-羟基酸. 研究发现，Zn-CA-MOFs化合物可以作为催化剂参与5-取代1H-四唑和吡喃吡唑分子的合成，在短时间内选择性、高效、收率高。如前所述，该催化剂表现出出色的可重复使用性和稳定性，并且可以循环使用多达五次而不会显着降低反应性。
• A highly sensitive and selective off–on fluorescent chemosensor for Al3+ based on naphthalene derivative
  作者：Reza Azadbakht、Javad Khanabadi

  DOI：10.1016/j.inoche.2013.01.009

  日期：2013.4

  A new dialdehyde (D) containing two emissive naphthalene and its [1+1] macrocycle with 1,2-diaminopropane were synthesized and characterized. The macrocycle was studied by H-1 NMR, C-13 NMR, COSY, HSQC, DEPT, mass spectrometry and microanalysis. The influence of metal cations such as Na+, K+, Cs+, Mg2+, Ba2+, Al3+, Pb2+, Cr3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Ag+ on the photophysical properties of the macrocyclic system in DMF and DMF/H2O (9:1, v/v) mixture was investigated by means of emission spectrophotometry. The macrocycle L was found to be as an effective fluorescent sensor for Al3+ ions. (C) 2013 Elsevier B.V. All rights reserved.
• Synthesis and characterization of a new organic nanoparticle as fluorescent chemosensor for aluminum ions
  作者：Reza Azadbakht、Mohammad Talebi、Javad Karimi、Reza Golbedaghi

  DOI：10.1016/j.ica.2016.09.042

  日期：2016.11

  A new macrocyclic ligand (L) was synthesized and characterized with spectroscopic techniques. Its nanoparticles were prepared by nanoprecipitation method. The averaged size of the synthesized nanoparticles in the optimized conditions was about 50 nm. The nanoparticles exhibit an "off-on" type mode with high selectivity in the presence of Al3+ ions. The organic nanoparticles (L) could be used as Al3+ chemosensor in aqueous media. Upon binding of Al3+ with the nanoparticles, a significant fluorescence enhancement with a turn-on ratio over 15-fold was triggered. However, other metal ions had no such significant effect on the nano-chemosensor. The detection limit of nanoparticles L for Al3+ was as low as 2.8 x 10(-7) M. Application of the nano-chemosensor (L) was also studied as molecular logic gate. (C) 2016 Elsevier B.V. All rights reserved.