| 947230-87-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 947230-87-7
• 化学式: C₄CuN₄*C₆H₁₇N₃*Cu
• 分子量: 362.384
• InChiKey: ZWURBFKCDLGVTK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3,3'-二氨基二丙基胺 、 potassium cyanide 、 copper(II) choride dihydrate 以 水 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  Assembly of cyano-bridged Cu(II)/Cu(II) and Cu(I)/Cu(II) compounds obtained by controlled ration of cyanide

  摘要：

  One reaction system of Cu(2+), dipn, and CN(-) with two different molar ratio sets of 1: 1: 5, and 2:1:8 produced two compounds I [Cu(II)- (dipn)][Cu(II)(CN)(I)(4)], and 2 [Cu(II)(dipn)](2)[CU(4)(I)(CN)(8)]center dot 2H(2)O, respectively (dipn = dipropylenetriamine). Their structures were determined 4 by X-ray crystallography. Compound 2 is built from Cu(I) and Cu(II) centers, which are bridged by cyanide groups and metal-metal bonds. The magnetic properties of 1 and 2 were investigated in 2-300 K. Compound 1 exhibits an antiferromagnetic exchange interaction between copper(II) ions mediated by cyano-bridges. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.04.032