(5-ethyl-1,3-dioxan-5-yl)methyl-2-methyl acrylate | 132743-21-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: (5-ethyl-1,3-dioxan-5-yl)methyl-2-methyl acrylate
• 英文别名: (5-Ethyl-1,3-dioxan-5-yl)methyl 2-methylprop-2-enoate
• CAS: 132743-21-6
• 化学式: C₁₁H₁₈O₄
• 分子量: 214.262
• InChiKey: DXPXBCAAUYLHNY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸 、 5-乙基-1,3-二噁烷-5-甲醇 在 对甲苯磺酸 作用下， 生成 (5-ethyl-1,3-dioxan-5-yl)methyl-2-methyl acrylate
  参考文献：
  名称：

  一些基于多元醇缩醛及其衍生物的杂环化合物的生物活性

  摘要：

  体外研究了环状缩醛（五-和二季戊四醇、乙三醇和双甘油）和 5-乙基-5-羟甲基-1,3-二恶烷酯的生物活性。在 HEK293 和 SH-SY5Y 细胞系上建立了 5-乙基-5-羟甲基-1,3-二恶烷酯的细胞毒性特性。7,11,18,21-tetraoxaspiro-5,2,2,5-heneicosane, 2-[(5-ethyl-5-hydroxymethyl)-1,3-dioxan-2-yl]phenol, 4.4 的潜在抗氧化性能-[oxydi(methylene)]-bis-2-diisopropyl-1,3-dioxolane, 4,4_-[oxydi(methylene)]-bis-1,3-dioxolane, (5-ethyl-1,3-dioxan-使用氧化应激模型在体外建立了 5-yl)methyl-2-methyl 丙烯酸和双 (5-ethyl-1,3-dioxan-5-yl)methylmaleate。

  DOI：

  10.1007/s11094-020-02295-8

文献信息

• IMAGE FORMATION METHOD, DECORATIVE SHEET, DECORATIVE SHEET MOLDING, PROCESS FOR PRODUCING IN-MOLD MOLDED PRODUCT, IN-MOLD MOLDED PRODUCT, AND INK SET
  申请人：FUJIFILM Corporation

  公开号：US20150064398A1

  公开（公告）日：2015-03-05

  The object of the present invention is to provide an image formation method that can give an image that is excellent in terms of adhesion to a substrate, blocking resistance of a resulting printed material, and molding suitability, in particular vacuum forming properties, and that can suppress post-molding cracking of a molding. Disclosed is an image formation method comprising, in order, Step a: a step of applying Liquid A to a substrate, Step b: a step of irradiating the applied Liquid A with actinic radiation so as to carry out complete curing or semi-curing up to a degree of cure of at least 90%, Step c: a step of applying Liquid B to a cured layer of the completely cured or semi-cured Liquid A, and Step d: a step of completely curing Liquid A and Liquid B.

  本发明的目的是提供一种图像形成方法，该方法能够给出在粘附于基板、印刷材料的阻塞抵抗性和成型适应性方面表现优异的图像，特别是真空成型性能，并且能够抑制成型后的开裂。揭示了一种图像形成方法，包括以下步骤：步骤a：将液体A涂在基板上；步骤b：用光致辐射照射已涂覆的液体A，以进行完全固化或半固化，直至至少90％的固化度；步骤c：在完全固化或半固化的液体A的固化层上涂覆液体B；步骤d：完全固化液体A和液体B。
• INKJET INK COMPOSITION, INKJET RECORDING METHOD, AND PRINTED MATERIAL
  申请人：FUJIFILM CORPORATION

  公开号：US20140370250A1

  公开（公告）日：2014-12-18

  An object of the present invention is to provide an ink composition for inkjet recording that is excellent in terms of surface gloss and storage stability. Disclosed is an ink composition for inkjet recording comprising (Component A) a polymerizable compound, (Component B-1) an oxyl free radical-based polymerization inhibitor, (Component B-2) a phenol-based polymerization inhibitor, and (Component B-3) an amine-based polymerization inhibitor. The polymerizable compound (Component A) preferably comprises (Component A-1) a divinyl ether compound. The ink composition preferably further comprises (Component C) a polymerization initiator, and more preferably comprises (Component C-1) an acylphosphine-based polymerization initiator as the polymerization initiator (Component C).

  本发明的目的是提供一种墨水成分，用于喷墨记录，具有表面光泽和储存稳定性方面的优异性。本发明公开了一种喷墨记录用墨水成分，包括（组分A）可聚合化合物，（组分B-1）以氧自由基为基础的聚合抑制剂，（组分B-2）以酚为基础的聚合抑制剂，以及（组分B-3）以胺为基础的聚合抑制剂。可聚合化合物（组分A）优选包括（组分A-1）二乙烯醚化合物。墨水成分优选进一步包括（组分C）聚合引发剂，并且更优选地包括（组分C-1）以酰基膦为基础的聚合引发剂作为聚合引发剂（组分C）。
• Ink composition, inkjet recording method, printed material, and process for producing molded printed material
  申请人：FUJIFILM Corporation

  公开号：EP2042572A1

  公开（公告）日：2009-04-01

  An ink composition is provided that includes a perfluoroalkyl group-containing polymer, a polymerizable monomer, and a radical polymerization initiator, in which at least 80 wt % of the polymerizable monomer is a monofunctional polymerizable monomer selected from the group consisting of a monofunctional acrylate, a monofunctional methacrylate, a monofunctional vinyloxy compound, a monofunctional N-vinyl compound, a monofunctional acrylamide, and a monofunctional methacrylamide. There are also provided an inkjet recording method that includes a step of discharging the ink composition onto a recording medium and a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material obtained by the inkjet recording method, and a process for producing a molded printed material that includes a step of forming an image by discharging the ink composition onto a support by an inkjet method, a step of irradiating the image thus obtained with actinic radiation so as to cure the ink composition and obtain a printed material having the image cured on the support, and a step of molding the printed material.

  提供了一种墨水组合物，它包括含全氟化烷基的聚合物、可聚合单体和自由基聚合引发剂，其中至少80重量％的可聚合单体是从单官能丙烯酸酯、单官能甲基丙烯酸酯、单官能乙烯氧基化合物、单官能N-乙烯基化合物、单官能丙烯酰胺和单官能甲基丙烯酰胺组成的组中选出的单官能可聚合单体。还提供了一种喷墨记录方法，该方法包括将墨水组合物排放到记录介质上的步骤，以及通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤，通过该喷墨记录方法获得的印刷材料、以及一种用于生产模塑印刷材料的工艺，该工艺包括通过喷墨方法将墨水成分排放到支撑物上以形成图像的步骤，用放电辐射照射由此获得的图像以固化墨水成分并获得在支撑物上固化了图像的印刷材料的步骤，以及模塑印刷材料的步骤。
• White ink composition, inkjet recording method, and printed material
  申请人：FUJIFILM Corporation

  公开号：EP2042574A1

  公开（公告）日：2009-04-01

  A white ink composition for inkjet recording is provided that includes an acylphosphine-based photopolymerization initiator, a monomer having a heterocyclic skeleton, and a white colorant, the acylphosphine-based photopolymerization initiator having a content of 10 to 18 wt % relative to the ink composition. There are also provided an inkjet recording method that includes a step of discharging the white ink composition for inkjet recording onto a recording medium and a step of curing the white ink composition by irradiating the discharged white ink composition with actinic radiation, and a printed material formed by the inkjet recording method.

  提供了一种用于喷墨记录的白色墨水组合物，它包括酰基膦基光聚合引发剂、具有杂环骨架的单体和白色着色剂，酰基膦基光聚合引发剂相对于墨水组合物的含量为 10 至 18 wt %。此外，还提供了一种喷墨记录方法，该方法包括将用于喷墨记录的白色墨水组合物排放到记录介质上的步骤和通过用阳极辐射照射排放的白色墨水组合物来固化白色墨水组合物的步骤，以及由该喷墨记录方法形成的印刷材料。
• Ink composition, inkjet recording method, printed material, and molded printed material
  申请人：FUJIFILM Corporation

  公开号：EP2088176A1

  公开（公告）日：2009-08-12

  An ink composition is provided that includes (A) a compound having an ethylenically unsaturated double bond and a silicone chain, (B) a polymerizable monomer, and (C) a radical polymerization initiator, at least 75 wt % of the polymerizable monomer being a monofunctional polymerizable monomer selected from the group consisting of a monofunctional acrylate, a monofunctional methacrylate, a monofunctional vinyloxy compound, a monofunctional N-vinyl compound, a monofunctional ethylenically unsaturated carboxylic acid compound, a monofunctional acrylamide, and a monofunctional methacrylamide. There are also provided an inkjet recording method that includes (i-1) a step of discharging the ink composition onto a recording medium and (i-2) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material formed by employing the inkjet recording method, and a molded printed material formed by subjecting the printed material to molding.

  提供了一种油墨组合物，它包括(A)具有乙烯基不饱和双键和硅酮链的化合物，(B)可聚合单体，和(C)自由基聚合引发剂，其中至少 75 wt % 的可聚合单体是选自以下组别的单官能团可聚合单体单官能度甲基丙烯酸酯、单官能度乙烯氧基化合物、单官能度 N-乙烯基化合物、单官能度乙烯基不饱和羧酸化合物、单官能度丙烯酰胺和单官能度甲基丙烯酰胺。还提供了一种喷墨记录方法，该方法包括（i-1）将墨水组合物排放到记录介质上的步骤和（i-2）通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤、通过使用喷墨记录方法形成的印刷材料和通过使印刷材料成型而形成的成型印刷材料。