N,N'-dipentylbenzene-1,2-diamine | 1370557-61-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-dipentylbenzene-1,2-diamine
• 英文别名: 1-N,2-N-dipentylbenzene-1,2-diamine
• CAS: 1370557-61-1
• 化学式: C₁₆H₂₈N₂
• 分子量: 248.412
• InChiKey: LRYMRKAIOVYPFM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  18
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  戊醇 、 邻苯二胺 在 [((5-Me)PyNPPh₂)IrACHTUNGTRENUNG(cod)] 、 potassium tert-butylate 作用下， 以 二乙二醇二甲醚 为溶剂， 反应 48.0h， 以42%的产率得到N,N'-dipentylbenzene-1,2-diamine
  参考文献：
  名称：

  轻度反应条件下铱催化对称和不对称烷基化二胺的合成

  摘要：

  铱催化剂-通过阴离子P稳定，N配体-用于的对称和非对称单烷基化对位- ，间位-和邻-benzenediamines。苄基和脂族醇用作烷基化试剂。合成了28种衍生物。其中14种是新化合物。此外，药理学重要的二胺Dapson的烷基化®（氨苯砜）进行说明。合成了14种氨苯砜衍生物，其中9种为新化合物。

  DOI：

  10.1002/adsc.201100554

文献信息

• Lubricating compositions containing ashless catalytic antioxidant additives
  申请人：Patil Abhimanyu O.

  公开号：US20070265178A1

  公开（公告）日：2007-11-15

  The invention comprises lubricating compositions and hydraulic fluids containing N,N′-diaryl-o-phenylenediamine compounds that impart good levels of oxidation inhibition in the lubricants and hydraulic fluids. The invention further comprises a method of making N,N′-diaryl-o-phenylenediamine compounds.

  本发明包括含有N,N′-二芳基-邻-苯二胺化合物的润滑组合物和液压油，这些化合物在润滑剂和液压油中提供了良好的氧化抑制作用。本发明还涉及一种制造N,N′-二芳基-邻-苯二胺化合物的方法。
• LUBRICATING OIL COMPOSITIONS WITH ENGINE WEAR PROTECTION AND SOLUBILITY
  申请人：Schilowitz Alan M.

  公开号：US20160208186A1

  公开（公告）日：2016-07-21

  A method for improving wear control in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that includes a lubricating oil base stock as a major component; and at least one phosphazene represented by the formula as a minor component. In the above formula, Q is nitrogen, sulfur or oxygen; a is a value from about 2 to about 6, c is a value from about 2 to about 6, e is a value from about 2 to about 6, g is a value from about 2 to about 6, i is a value from about 2 to about 6, and k is a value from about 2 to about 6; b is a value of 2a+q, d is a value of 2c+r, f is a value of 2e+s, h is a value of 2g+t, j is a value of 2i+u, and l is a value of 2k+v; q, r, s, t, u and v are independently a value of 0 or −2; with the proviso that not all of a, c, e, g, i and k are the same value. A lubricating oil having a composition that includes a lubricating oil base stock as a major component; and at least one phosphazene represented by the above formula as a minor component. The lubricating oil is useful in internal combustion engines.

  一种用配制油作为润滑油来改善发动机或其他机械部件的磨损控制的方法。配制油的组成包括润滑油基础油作为主要成分；以及至少一种由上述公式表示的膦烷作为次要成分。在上述公式中，Q为氮、硫或氧；a值约为2至6，c值约为2至6，e值约为2至6，g值约为2至6，i值约为2至6，k值约为2至6；b值为2a+q，d值为2c+r，f值为2e+s，h值为2g+t，j值为2i+u，l值为2k+v；q、r、s、t、u和v独立取值为0或-2；但a、c、e、g、i和k不全为相同值。具有包括润滑油基础油作为主要成分和至少一种由上述公式表示的膦烷作为次要成分的润滑油组成。这种润滑油适用于内燃机。
• THERMOCLEAVABLE FRICTION MODIFIERS AND METHODS THEREOF
  申请人：Rutgers, The State University of New Jersey

  公开号：US20180037840A1

  公开（公告）日：2018-02-08

  Certain embodiments of the invention provide a lubricating oil composition comprising a lubricating oil base stock and a compound of formula (I): or a salt thereof, wherein R 1 , R 2 , R 3 and R 4 have any of the values defined in the specification, as well as methods of use thereof.

  该发明的某些实施例提供一种润滑油组合物，包括润滑油基础油和化合物的公式(I)：或其盐，其中R1、R2、R3和R4具有规范中定义的任何值，以及其使用方法。
• Organic Electroluminescent Devices
  申请人：Stoessel Philipp

  公开号：US20110201778A1

  公开（公告）日：2011-08-18

  The present invention relates to electronic devices, in particular organic electroluminescent devices, which comprise compounds of the formula (1), and to the corresponding compounds and to the use thereof in organic electroluminescent devices.

  本发明涉及电子设备，特别是包含式（1）化合物的有机电致发光装置，以及相应的化合物及其在有机电致发光装置中的使用。
• LOW TRANSITION TEMPERATURE MIXTURES OR DEEP EUTECTIC SOLVENTS AND PROCESSES FOR PREPARATION THEREOF
  申请人：Patil Abhimanyu O.

  公开号：US20160122676A1

  公开（公告）日：2016-05-05

  A low transition temperature mixture (LTTM) or deep eutectic solvent (DES) useful as a lubricating oil base stock and lubricating oil including a eutectic mixture of at least a first component and at least a second component. The at least first component comprises a hydrogen bond acceptor and the at least second component comprises a hydrogen bond donor. The eutectic mixture includes an equilibrium phase between the at least first component and the at least second component. The equilibrium phase does not exhibit physical characteristics of the at least first component in an unmixed state and the at least second component in an unmixed state. The at least first component and the at least second component form an intermolecular interaction between each other sufficient to prevent crystallization of the at least first component and the at least second component in the eutectic mixture. The eutectic mixture is a liquid at 20° C.

  一种低转变温度混合物（LTTM）或深共晶溶剂（DES），可用作润滑油基础油和润滑油，包括至少第一组分和至少第二组分的共晶混合物。至少第一组分包括氢键受体，至少第二组分包括氢键给体。共晶混合物包括至少第一组分和至少第二组分之间的平衡相。平衡相在未混合状态下不表现出至少第一组分和至少第二组分的物理特性。至少第一组分和至少第二组分之间形成一种分子间相互作用，足以防止共晶混合物中至少第一组分和至少第二组分的结晶。共晶混合物在20℃时是液态的。