3-Triphenylmethylinden | 138036-88-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 3-Triphenylmethylinden
• 英文别名: 3-trityl-1H-indene
• CAS: 138036-88-1
• 化学式: C₂₈H₂₂
• 分子量: 358.483
• InChiKey: NJRFNPIRWLMFPM-UHFFFAOYSA-N

物化性质

• 沸点：
  519.8±50.0 °C(Predicted)
• 密度：
  1.137±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.66
• 重原子数：
  28.0
• 可旋转键数：
  4.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  三苯基氯甲烷 、 茚 生成 3-Triphenylmethylinden
  参考文献：
  名称：

  Meurling,L., Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1974, vol. 28, p. 295 - 300

  摘要：

  DOI：

文献信息

• Phase transfer catalyzed tert-alkylations of cyclopentadiene and indene: indications for set processes
  作者：Eckehard V. Dehmlow、Christof Bollmann

  DOI：10.1016/s0040-4039(00)93552-4

  日期：1991.10

  Scope and mechanism of the PTC tert-alkylation of cyclopentadienide anion have been investigated. On the side of the anion, the reaction is limited to cyclopentadiene and indene, whereas many tertiary as well as secondary and primary alkylating agents can be employed. Hexamethylcyclopentadiene 8, for instance, is available easily. Tert-alkylations of this type are more effective if 4,4'-bipyridinium salts are present in addition to a phase transfer catalyst. The reactions involve probably an initial single electron transfer (SET) step.