(R)-(-)-[1-cyclohexylethyl]salicylaldimine | 527731-19-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: (R)-(-)-[1-cyclohexylethyl]salicylaldimine
• 英文别名: 6-({[(1R)-1-Cyclohexylethyl]amino}methylidene)cyclohexa-2,4-dien-1-one；2-[[(1R)-1-cyclohexylethyl]iminomethyl]phenol
• CAS: 527731-19-7
• 化学式: C₁₅H₂₁NO
• 分子量: 231.338
• InChiKey: GREZNKALTFQFLK-GFCCVEGCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  copper(II) acetate monohydrate 、 (R)-(-)-[1-cyclohexylethyl]salicylaldimine 在 Et₃N 作用下， 以 二氯甲烷 为溶剂， 生成 bis[(R)-(1-cyclohexylethyl)-salicylaldiminato]copper(II)
  参考文献：
  名称：

  New chiral Schiff base–Cu(II) complexes as cyclopropanation catalysts

  摘要：

  A series of chiral Schiff base ligands 1-4, derived from (1R,2S)-(+)-cis-1-amino-2-indanol and other chiral amines with substituted salycilaldehydes were synthesized and transformed to the corresponding CU(II) complexes. Molecular structures of six Cu(II) complexes were determined by X-ray crystallographic studies. The structures show the metal ion in a distorted square planar geometry with dimeric or monomeric structures, depending on the ligand denticity. The potential use of these complexes in asymmetric Cyclopropanation was explored. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.09.007