摘要:
Xe (OTeF5) 2 在形成[Xe2 (OTeF5) 3] + [Sb (OTeF5) 6] - 的情况下与Sb (OTeF5) 3 反应。从 SO2ClF 溶液中形成黄色溶剂化物 [F5TeOXe] + SO2ClF [Sb (OTeF5) 6] - 形成晶体数据:a = 1028.1 (1), b = 1040.9 (1), c = 1780.2 (3) pm, α = 98.07 (1), β = 97.68 (1), γ = 105.82 (1) °, 空间群。O-Xe…O片段基本上是线性的(176.1(2)°),两个Xe-O距离相差很大197.1(4)和242.6(4)pm。[(F5TeOXe) + · SO2ClF] [Sb (OTeF5) 6-] Xe (OTeF5) 2 的形成和晶体结构与Sb (OTeF5) 3 反应形成[Xe2 (OTeF5) 3] + [Sb (OTeF5)