trichloro-2κ(3)Cl-(5,10,15,20-tetraphenylporphyrinato-1κ(4)N(21,22,23,24))rhodium(III)tin(II)(Rh-Sn) | 115557-44-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: trichloro-2κ(3)Cl-(5,10,15,20-tetraphenylporphyrinato-1κ(4)N(21,22,23,24))rhodium(III)tin(II)(Rh-Sn)
• 英文别名: trichlorotin(II)-(meso-tetraphenylporphyrinato)rhodium(III)
• CAS: 115557-44-3
• 化学式: C₄₄H₂₈Cl₃N₄RhSn
• 分子量: 940.708
• InChiKey: GWJKQNATEMKKEA-FLYAKZGESA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (5,10,15,20-tetraphenylporphyrinato)rhodium(III) chloride 、 tin(ll) chloride 以 四氢呋喃 为溶剂， 生成 trichloro-2κ(3)Cl-(5,10,15,20-tetraphenylporphyrinato-1κ(4)N(21,22,23,24))rhodium(III)tin(II)(Rh-Sn)
  参考文献：
  名称：

  Synthesis and characterization of novel rhodium porphyrin derivatives with a metalmetal bond

  摘要：

  DOI：

  10.1016/s0020-1693(00)82000-9

文献信息

• Trichlorotin(II)–(meso-Tetraphenylporphyrinato)rhodium(III), a Porphyrin Derivative with an Rh—Sn Bond
  作者：S. Licoccia、R. Paolesse、T. Boschi、G. Bandoli、A. Dolmella

  DOI：10.1107/s0108270194012424

  日期：1995.5.15

  The structure of the title compound, trichloro-2 kappa(3)Cl-(5,10,15,20-tetraphenylporphyrinato- 1 kappa(4)N(21,22,)(23,24))rhodium(III)tin(II)(Rh-Sn), [RhSnCl3(C44H28N4)], consists of well separated units in which the Rh atom is five-coordinate at the center of a square-pyramidal polyhedron with the Sn atom at the top. The macrocylic unit is planar with the Rh atom displaced by only 0.02 Angstrom from the ring plane. The Rh-Sn bond length is 2.450 (1) Angstrom.