1,3,4,6-tetraaminohexane | 1289535-26-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,3,4,6-tetraaminohexane
• 英文别名: hexane-1,3,4,6-tetramine
• CAS: 1289535-26-7
• 化学式: C₆H₁₈N₄
• 分子量: 146.236
• InChiKey: HHKIGDGJLABVRO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.7
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  104
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4,4',5,5'-tetrahydro-3H,3'H-3,3'-bipyrazole 在 氢气 作用下， 以 甲醇 为溶剂， 100.0 ℃ 、13.0 MPa 条件下， 反应 6.0h， 以99%的产率得到1,3,4,6-tetraaminohexane
  参考文献：
  名称：

  Catalytic synthesis of 1,3-propylenediamines

  摘要：

  The hydrogenation on Raney nickel of 3-alkenyl-substituted pyrazolines and also of 3-methyl-5-(2-furyl)-1H-pyrazoline and 3,3'-bipyrazoline afforded substituted 1,3-diaminobutanes, 1,3-diaminopentanes, 1,3-diaminohexane, and 1,3,4,6-tetraaminohexane. Under the same conditions from 3-acetyl-4-(2-furyl)-1H-pyrazoline 3-amino-2-methyl-4-(2-furyl) pyrrolidine was obtained.

  DOI：

  10.1134/s1070428011020035

文献信息

• FLUORINATED SULFONATE ESTERS OF ARYL KETONES FOR NON-IONIC PHOTO-ACID GENERATORS
  申请人：International Business Machines Corporation

  公开号：US20180046077A1

  公开（公告）日：2018-02-15

  Non-ionic photo-acid generating (PAG) compounds were prepared that contain an aryl ketone group having a perfluorinated substituent alpha to the ketone carbonyl. The non-polymeric PAGs release a sulfonic acid when exposed to high energy radiation such as deep UV or extreme UV light. The photo-generated sulfonic acid has a low diffusion rate in an exposed resist layer subjected to a post-exposure bake (PEB) at 100° C. to 150° C., resulting in formation of good line patterns after development. At higher temperatures, the PAGs can also undergo a thermal reaction to form a sulfonic acid. The perfluorinated substituent provides improved thermal stability and hydrolytic/nucleophilic stability.

  非离子型光生酸(PAG)化合物被制备出来，它们含有一个含有全氟取代基的芳酮基团，该取代基位于酮羰基的α位置。这些非聚合PAGs在暴露于高能辐射，如深紫外或极紫外光时，会释放出磺酸。在100°C至150°C的后曝光烘烤(PEB)下，光生成的磺酸在暴露的抵抗层中具有较低的扩散速率，从而在开发后形成良好的线条图案。在较高温度下，PAGs也可以通过热反应形成磺酸。全氟取代基提供了改善的热稳定性和水解/亲核稳定性。
• NON-IONIC LOW DIFFUSING PHOTO-ACID GENERATORS
  申请人：International Business Machines Corporation

  公开号：US20180044284A1

  公开（公告）日：2018-02-15

  Non-ionic photo-acid generating (PAG) compounds were prepared that contain an aryl ketone group. The disclosed non-polymeric PAGs release a strong sulfonic acid when exposed to high energy radiation such as deep UV or extreme UV light. The photo-generated sulfonic acid has a low diffusion rate in an exposed resist layer subjected to a post-exposure bake (PEB) at 100° C. to 150° C., resulting in formation of good line patterns after development. At higher temperatures, the PAGs undergo a thermal reaction to form a sulfonic acid.

  制备了含芳基酮基团的非离子光酸发生（PAG）化合物。揭示的非聚合物PAG在暴露于高能辐射（如深紫外或极紫外光）时释放出强磺酸。光生磺酸在经过后曝光烘烤（PEB）处理（在100°C至150°C下）的受暴露光阻层中具有低扩散速率，从而在显影后形成良好的线条图案。在较高温度下，PAG会发生热反应形成磺酸。
• Process for the Synthesis of N-substituted Cyclic Alkylene Ureas
  申请人：Cytec Technology Corp.

  公开号：EP2548869A1

  公开（公告）日：2013-01-23

  The invention relates to a process for the synthesis of N-substituted cyclic alkylene ureas by reacting a multifunctional aliphatic amine A having at least two amino groups which may be primary or secondary, at least one of which is a primary amino group, -NH2, and at least one of which is a secondary amino group, >NH, the other hydrogen group whereof having been substituted by a hydrocarbyl group which in turn may be substituted by a hydroxyl group, or an amino group, or a carboxyl group, or a ketone carbonyl group, or a hydrazide or hydrazone group, or a mercaptan group, and at least one further functional group selected from the group consisting of primary or secondary amino groups and hydroxyl groups, and an aliphatic organic carbonate component C selected from the group consisting of dialkyl carbonates CD and of alkylene carbonates CA.

  本发明涉及一种合成N-取代环状烷基脲的方法，该方法通过反应一种具有至少两个氨基的多功能脂肪族胺A来实现，其中至少一个是一级氨基-NH2，至少一个是二级氨基->NH，其它氢原子被烃基取代，该烃基又可以被羟基、氨基、羧基、酮羰基、肼或肼酮基、巯基取代，同时还包括至少一种来自于一级或二级氨基与羟基的功能基团，以及一种来自于脂肪族有机碳酸酯组分C的反应，该组分C选自双烷基碳酸酯CD和烷基碳酸酯CA的组合。
• [EN] PROCESS FOR THE SYNTHESIS OF N-SUBSTITUTED CYCLIC ALKYLENE UREAS<br/>[FR] PROCÉDÉ POUR LA SYNTHÈSE D'ALKYLÈNE-URÉES N-SUBSTITUÉES CYCLIQUES
  申请人：CYTEC TECH CORP

  公开号：WO2013012995A1

  公开（公告）日：2013-01-24

  The invention relates to a process for the synthesis of N-substituted cyclic alkylene ureas by reacting a multifunctional aliphatic amine A having at least two amino groups which may be primary or secondary, at least one of which is a primary amino group, -NH2, and at least one of which is a secondary amino group, >NH, the other hydrogen group whereof having been substituted by a hydrocarbyl group which in turn may be substituted by a hydroxyl group, or an amino group, or a carboxyl group, or a ketone carbonyl group, or a hydrazide or hydrazone group, or a mercaptan group, and at least one further functional group selected from the group consisting of primary or secondary amino groups and hydroxyl groups, and an aliphatic organic carbonate component C selected from the group consisting of dialkyl carbonates CD and of alkylene carbonates CA.

  本发明涉及一种合成N-取代的环烷基脲的方法，包括将至少具有两个氨基团的多功能脂肪族胺A进行反应，其中至少一个是一级氨基团-NH2，至少一个是二级氨基团->NH，其它氢原子已被烃基取代，该烃基又可以被羟基、氨基、羧基、酮羰基、肼或肼酮基、巯基取代，同时还具有来自于一级或二级氨基团和羟基团的至少一个进一步的功能团，以及从二烷基碳酸酯CD和烷基碳酸酯CA组成的脂肪族有机碳酸酯组分C进行反应。
• Schalldämpfendes Polyurethan
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：EP1022297A1

  公开（公告）日：2000-07-26

  Die Erfindung betrifft ein Verfahren zur Herstellung eines Polyurethans mit einem Verlustfaktor im Bereich von 0,2 bis 0,8 durch in Kontakt bringen von mindestens einer eine gegenüber Isocyanaten reaktive Verbindung aufweisenden Komponente A und einer Polyisocyanate aufweisenden Komponente B.

  本发明涉及一种生产聚氨酯的工艺，该聚氨酯的损耗因子在 0.2 至 0.8 之间，生产工艺是将至少一种由对异氰酸酯有反应性的化合物组成的 A 组分和由多异氰酸酯组成的 B 组分接触在一起。