| 369361-36-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• CAS: 369361-36-4
• 化学式: C₁₇H₁₈N₂OS₂
• 分子量: 330.475
• InChiKey: PJAKWRCHETTXFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.31
• 重原子数：
  22.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  44.62
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  bis(acetylacetonato)dioxidomolybdenum(VI) 、 乙醇 、 以 乙醇 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF SOME DIOXOMOLYBDENUM(VI) COMPLEXES WITH O, N, S DONOR SCHIFF BASES DERIVED FROM S-METHYLDITHIOCARBAZATE, S-BENZYLDITHIOCARBAZATE, 2-AMINOETHANETHIOL, AND SUBSTITUTED SALICYLALDEHYDES

  摘要：

  Synthesis and characterization of some dioxomolybdenum(VI) complexes which can be represented by the general formulae MoO2(L)(EtOH) (where LH2 = Schiff base derived from o-hydroxyacetophenone (hap), o-hydroxypropiophenone (hpp), and S-methyldithiocarbazate (SMDTC), S-benzyldithiocarbazate (SBDTC) and 2-aminoethanethiol (AmET)) are reported. The various Schiff base ligands prepared by condensation of appropriate amino compounds and substituted salicylaldehydes are H(2)hap-SBDTC (1a), H(2)hpp-SBDTC (2a), H(2)hpp-SMDTC (3a), H(2)hap-SMDTC (4a), H(2)hap-AmET (5a) and H(2)hpp-AmEt (6a). The various Schiff base complexes prepared by reacting cis-MoO2(acaC)(2) and the ligands (1a)-(6a) are MoO2 (hap-SBDTC)(EtOH) (1b), MoO2(hpp-SBDTC)(EtOH) (2b) MoO2(hpp)-SMDTC)(EtOH) (3b), MoO2(hap-SMDTC)(EtOH) (4b), MoO2(hap-AmET)(EtOH) (5b) and MoO2(hpp-AmET) (EtOH) (6b). These complexes have been characterized by elemental analyses, UV-Vis, IR, NMR, AAS, TGA and conductivity measurements. The complexes are monomers nonelectrolytes, diamagnetic and six-coordinated. The Schiff bases behave as dibasic tridentate ligands and coordinate through the phenolic oxygen, thioenolic sulfur and azomethine nitrogen atoms.

  DOI：

  10.1081/sim-100104856