N-(4-(Bis(4-(hydroxy)phenyl)amino)phenyl)2-chloroacetamide | 1256087-75-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(4-(Bis(4-(hydroxy)phenyl)amino)phenyl)2-chloroacetamide
• 英文别名: 2-chloro-N-[4-(4-hydroxy-N-(4-hydroxyphenyl)anilino)phenyl]acetamide
• CAS: 1256087-75-8
• 化学式: C₂₀H₁₇ClN₂O₃
• 分子量: 368.82
• InChiKey: PDZJNQTZWLYLSS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  72.8
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-(4-amino-N-(4-hydroxyphenyl)anilino)phenol 、 氯乙酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 生成 N-(4-(Bis(4-(hydroxy)phenyl)amino)phenyl)2-chloroacetamide
  参考文献：
  名称：

  电荷纳米载体的分层自组装：可见光促进的高度合作过程

  摘要：

  让更多的光发出来：基于三芳基胺的结构单元通过形成阳离子自由基而对可见光作出响应，这些阳离子自由基自组装成分子丝，并依次结合在较大的纤维中（参见图片）。通过电荷转移产生的刺激响应性超分子支架可通过加热可逆地破坏，从而防止导线中的孔淬灭。

  DOI：

  10.1002/anie.201001833

文献信息

• Electric Conduction Through Supramolecular Assemblies of Triarylamines
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S)

  公开号：US20150298092A1

  公开（公告）日：2015-10-22

  A method is provided for modifying a surface of a solid conducting material, which includes applying a potential difference between this surface and a surface of another conducting solid material positioned facing it, and wherein, simultaneously, the surface (S) is put into contact with a liquid medium comprising in solution triarylamines (I): while subjecting these triarylamines (I) to electromagnetic radiation, at least partly converting them at into triarylammonium radicals. Also provided is a conducting device which includes two conducting metal materials, the surfaces of which, (S) and (S′) respectively, are electrically interconnected through an organic material comprising conducting fibrillar organic supramolecular species comprising an association of triarylamines of formula (I).
• US9849437B2
  申请人：——

  公开号：US9849437B2

  公开（公告）日：2017-12-26
• The Hierarchical Self-Assembly of Charge Nanocarriers: A Highly Cooperative Process Promoted by Visible Light
  作者：Emilie Moulin、Fréderic Niess、Mounir Maaloum、Eric Buhler、Irina Nyrkova、Nicolas Giuseppone

  DOI：10.1002/anie.201001833

  日期：2010.9.17

  Let there be more light: Triarylamine‐based building blocks respond to visible‐light exposure by the formation of cationic radicals that hierarchically self‐assemble into molecular wires, which in turn combine within larger fibers (see picture). The stimuli‐responsive supramolecular scaffold, which is created by charge transfer and reversibly broken up by heating, prevents the quenching of holes within

  让更多的光发出来：基于三芳基胺的结构单元通过形成阳离子自由基而对可见光作出响应，这些阳离子自由基自组装成分子丝，并依次结合在较大的纤维中（参见图片）。通过电荷转移产生的刺激响应性超分子支架可通过加热可逆地破坏，从而防止导线中的孔淬灭。