2-[(1-((3-(5-hydroxy)oxa)pentyl)imine)ethyl]phenol | 744233-04-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-[(1-((3-(5-hydroxy)oxa)pentyl)imine)ethyl]phenol
• CAS: 744233-04-3
• 化学式: C₁₂H₁₇NO₃
• 分子量: 223.272
• InChiKey: FTJAIJUCHGNDDQ-UHFFFAOYSA-N

物化性质

• 熔点：
  45-46 °C
• 沸点：
  362.3±42.0 °C(Predicted)
• 密度：
  1.10±0.1 g/cm3(Predicted)

反应信息

• 作为反应物：
  描述：

  2-[(1-((3-(5-hydroxy)oxa)pentyl)imine)ethyl]phenol 、 苯硼酸 以 四氢呋喃 为溶剂， 以61%的产率得到2-phenyl-10-methylbenzo[k]-9-aza-1,3,6-trioxa-2-boracyclododeca-9-ene
  参考文献：
  名称：

  Bisoxazaborolidines and boron complexes derived from tetradentate ligands: synthesis and spectroscopic studies

  摘要：

  A series of tetradentate ligands were synthesized and their reaction with arylboronic acids was studied. Two classes of tetradentate ligands are discussed, which are mainly based on ONNO and ONOO donor sets and involve 2-aminophenol derivatives and Schiff bases. The reaction of phenylboronic acid with tetradentate ligands derived from 2-aminophenol leads to bisoxazaborolidines containing five-membered rings formed by CCNBO atoms, where the boron atoms have a trigonal geometry. In contrast, tetradentate ligands derived from Schiff bases lead to monomeric and dimeric boron complexes, in which the boron atoms have a tetrahedral geometry stabilized by an intramolecular N-B dative bond. The structures of two boron compounds were established by X-ray diffraction analysis. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.02.018