| 64591-11-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 大环内酰胺类
• CAS: 64591-11-3
• 化学式: C₂₉H₄₆N₂O₅
• 分子量: 502.695
• InChiKey: OSOULEAGYKHLMZ-GCWYWQLASA-N

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 生成 4-[(2R,3S,3aR,5aS,6R,7R,8aS,8bS)-6-Ethyl-2-(3-methoxycarbonyl-propyl)-7-methyl-dodecahydro-as-indacen-3-yl]-butyric acid methyl ester
  参考文献：
  名称：

  The Structure of Ikarugamycin, an Acyltetramic Acid Antibiotic Possessing a Uniqueas-Hydrindacene Skeleton

  摘要：

  The structure and configuration of an antibiotic, ikarugamycin, have been established to be 1e on the basis of chemical reactions, especially of oxidative degradation. It is suggested that the as-hydrindacene skeleton arises biogenetically via an intramolecular Diels-Alder reaction.

  DOI：

  10.1246/bcsj.50.1813