[(N,N-dimethyl-1-naphthylamine)Pd(μ-Cl)]2 | 18987-72-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [(N,N-dimethyl-1-naphthylamine)Pd(μ-Cl)]2
• 英文别名: [(Pd(C,N-C10H6N(CH3)2)(μ-Cl))2]；chloropalladium(1+);N,N-dimethyl-8H-naphthalen-8-id-1-amine
• CAS: 18987-72-9
• 化学式: C₂₄H₂₄Cl₂N₂Pd₂
• 分子量: 624.214
• InChiKey: GGMJXSGDLHRQJT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(N,N-dimethyl-1-naphthylamine)Pd(μ-Cl)]2 、 Ph2PCH2N(H)C5H3(OH)N 以 二氯甲烷 为溶剂， 以81%的产率得到[PdCl(C,N-C10H6N(CH3)2)(Ph2PCH2N(H)C5H3N(OH))]
  参考文献：
  名称：

  新型氨基醇官能化叔膦的合成及配位研究

  摘要：

  报道了两种新的氨基醇官能化叔膦 o-Ph2PCH2N(H)C6H4(OH) (I) 和 o-Ph2PCH2N(H)C6H4(CH2OH) (II) 的合成。用 H2O2 水溶液氧化得到相应的氧化膦 o-Ph2P(O)CH2N(H)C6H4(OH) (III) 和 o-Ph2P(O)CH2N(H)C6H4(CH2OH) (IV)（P-31 NMR 证据）只要）。用一系列后期过渡金属前体研究了 I、II 以及在几种情况下已知配体 2,3-Ph2PCH2N(H)C5H3N(OH)(V) 的连接能力。因此，2 当量的 I（或 II）与 [MCl2(cod)]（M = Pd 或 Pt，cod = cycloocta-1,5-diene）反应得到相应的二氯金属（II）配合物 [MCl2(I) (2)] (M = Pd 1; M = Pt 2) 和 [MCl2(II)(2)] (M = Pd 3; M =

  DOI：

  10.1139/v01-037

文献信息

• Neutral Organometallic Palladium(II) Aquo Complexes
  作者：Camino Bartolomé,、Pablo Espinet、Laura Vicente、Fernando Villafañe、Jonathan P. H. Charmant、A. Guy Orpen

  DOI：10.1021/om020198r

  日期：2002.8.19

  The reactions of chlorobridged cyclometalated complexes [Pd(C-N)(mu-Cl)](2) (C-N = orthometalated N,N-dimethylbenzylamine, dmba; 2-(para-tolyl)pyridine, p-tolpy; azobenzene, azb; N,N-dimethyl-1-naphthylamine, dmna; and 2-benzylpyridine, bzpy) with Li(Fmes) (Fimes = 2,4,6-tris(trifluoromethyl)phenyl or nonafluoromesityl) give, after hydrolysis, neutral aquo complexes [Pd(C-N)(Fmes)(OH2)] where the ipso carbon atoms of the Fines and the cyclometalated ligand are coordinated cis, as shown by an X-ray diffraction study of [Pd(dmba)(Fmes)(OH2)]. The aquo ligand is readily displaced by other ligands, giving complexes [Pd(C-N)(Fmes)L] (1, = PPh3, 2,6-lutidine, NH3, (CNBu)-Bu-t, CO) when monodentate ligands are employed or [Pd(dmba-C)(Fmes)(2,2'-bipy)], which contains a chelating 2,2'-bipyridyl and a monodentate C-bonded dmba, Different processes in solution are detected for the complexes containing the bulkier ligands: ligand rotation in the complex with PPh3; inversion of the bipy ligand in [Pd(dmba-C(Fmes)(2,2'-bipy)1; and equilibria with residual water in the solutions of [Pd(C-N)(Fmes)(lut)1 and [Pd(dmba-C)(Fmes)(2,2-bipy)].