hydroxo(pyridine)phthalocyaninatomanganese(III) | 108986-13-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: hydroxo(pyridine)phthalocyaninatomanganese(III)
• CAS: 108986-13-6
• 化学式: C₃₇H₂₂MnN₉O
• 分子量: 663.579
• InChiKey: HJYLNFFUCMXRPE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  μ-oxo-bis((pyridine)(phthalocyaninato)manganese(III)) 在 air 作用下， 以 吡啶 为溶剂， 生成 hydroxo(pyridine)phthalocyaninatomanganese(III)
  参考文献：
  名称：

  Synthesis, structural investigations and magnetic properties of dipyridinated manganese phthalocyanine, MnPc(py)2

  摘要：

  The MnPc(py)(2) complex was obtained in the reaction of MnPc with purified and dry pyridine under non-oxidation conditions. It crystallises in the centrosymmetric space group P2(1)/c of the monoclinic system with two molecules per unit cell. The Mn2+ cation is coordinated by four N-isoindole atoms of phthalocyaninato(2-) macrocycle and axially by two nitrogen atoms of pyridine molecules into a tetragonal bipyramid. The MnPC(py)(2) crystals are moderately stable under air, but in pyridine solution the MnPC(py)2 complex undergoes oxidation by O-2 Yieldings the binuclear manganese(III) mu-oxo complex (MnPcpy)(2)O as evidenced by the UV-Vis spectroscopy. The magnetic susceptibility measurement performed on solid sample of MnPC(py)(2) shows the Curie-Weiss behaviour in the temperature region of 300-15 K. The calculated magnetic moment mu(eff) indicates three impaired electrons (S = 3/2), thus the ground state configuration of Mn ion is (a(Ig))(2)(e(g))(2)(b(2g))(1), and the MnPc(py)(2) complex is the intermediate spin complex. Below 5.5 K (T-N) the magnetic susceptibility sharply decreases due to the cooperative intermolecular antiferromagnetic interactions. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00361-9