[copper(II)(1,4,8,9-tetranitrotrisphene)(1,4-benzenedicarboxylate)(H2O)] | 944071-82-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [copper(II)(1,4,8,9-tetranitrotrisphene)(1,4-benzenedicarboxylate)(H2O)]
• CAS: 944071-82-3
• 化学式: C₂₂H₁₄CuN₄O₅
• 分子量: 477.923
• InChiKey: JYVWKXRVLNDCII-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 对苯二甲酸 、 水 、 吡嗪并[2，3-f]的[1，10]菲咯啉 在 NaOH 作用下， 以 水 为溶剂， 以58%的产率得到[copper(II)(1,4,8,9-tetranitrotrisphene)(1,4-benzenedicarboxylate)(H2O)]
  参考文献：
  名称：

  Influence of the size of aromatic chelate ligands on the one-dimensional chains of copper(II) dicarboxylate coordination polymers

  摘要：

  To investigate the influence of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers, two one-dimensional coordination compounds [Cu(BDC)(TATP)(H2O)] (n) (I) and [Cu(BDC)(DPPZ)] (n) (II), (BDC = 1.4-benzenedicarboxylate, TATP = 1,4,8,9-tetranitrogentrisphene, DPPZ = dipyrido[3,2-a:2',3'-c]phenazine) were synthesized under similar conditions and structurally characterized by X-ray crystallography. Compounds I and II have the similar zigzag chain structure, but the substitution of TATP with DPPZ results in the difference of the degree of bending of the chain, indicating that the sizes of the rigid aromatic chelate ligands have important effect on the structures of their complexes.

  DOI：

  10.1134/s1070328409090127